!version: dme_24 !Kaiser, E.W., Wallington, T.J., Hurley, M. D., Platz, J., Curran, H. J., Pitz, W. J., and Westbrook, C. K., !"Experimental and Modeling Study of Premixed Atmospheric-Pressure Dimethyl Ether-Air Flames", !Journal of Physical Chemistry, A 104, No. 35, 8194-8206, 2000; !Lawrence Livermore National Laboratory, Livermore, CA, UCRL-JC-136123 !Last modified: Aug 19, 1999. !UCRL-WEB-204236 !Review and release date: May 19, 2004. ! elements h c o n end species h h2 o o2 oh h2o n2 co hco co2 ch3 ch4 ho2 h2o2 ch2o ch3o c2h6 c2h4 c2h5 ch2 ch c2h c2h2 c2h3 ch3oh ch2oh ch2co hcco c2h5oh pc2h4oh sc2h4oh ch3co ch2cho ch3cho ch3coch3 ch3coch2 c2h5cho c2h5co c2h5o ch3o2 c2h5o2 ch3o2h c2h5o2h c2h3o1-2 ch3co2 c2h4o1-2 c2h4o2h o2c2h4oh ch3co3 ch3co3h c2h3co c2h3cho ch3coch2o2 ch3coch2o2h ch3coch2o hco3h hco3 hco2 o2c2h4o2h ch2(s) ch3och3 ch3och2 ch3och2o2 ch2och2o2h ch3och2o2h ch3och2o o2ch2och2o2h ho2ch2ocho och2ocho hoch2oco hoch2o hco2h ch3ocho ch3oco ch2ocho ch3och2oh hoch2o2h och2o2h hoch2o2 end reactions cal/mole ch3+h(+m) = ch4(+m) 2.140e+15 -0.40 0.000E+00 low/3.31e+30 -4.0 2108./ troe/0.0 1.e-15 1.e-15 40./ h2/2/ h2o/5/ co/2/ co2/3/ ch4+h = ch3+h2 1.727E+04 3.00 8.224E+03 rev / 6.610E+02 3.00 7.744E+03 / ch4+oh = ch3+h2o 1.930E+05 2.40 2.106E+03 rev / 4.820E+02 2.90 1.486E+04 / ch4+o = ch3+oh 2.130E+06 2.21 6.480E+03 rev / 3.557E+04 2.21 3.920E+03 / c2h6+ch3 = c2h5+ch4 1.510E-07 6.00 6.047E+03 rev / 9.649E-10 6.56 1.022E+04 / hco+oh = co+h2o 1.020E+14 0.00 0.000E+00 rev / 2.896E+15 0.00 1.052E+05 / co+oh = co2+h 1.400E+05 1.95 -1.347E+03 rev / 1.568E+07 1.95 2.099E+04 / h+o2 = o+oh 1.970E+14 0.00 1.654E+04 rev / 1.555E+13 0.00 4.250E+02 / o+h2 = h+oh 5.080E+04 2.67 6.292E+03 rev / 2.231E+04 2.67 4.197E+03 / o+h2o = oh+oh 2.970E+06 2.02 1.340E+04 rev / 3.013E+05 2.02 -3.850E+03 / oh+h2 = h+h2o 2.160E+08 1.51 3.430E+03 rev / 9.352E+08 1.51 1.858E+04 / hco+m = h+co+m 1.860E+17 -1.00 1.700E+04 rev / 6.467E+13 0.00 -4.420E+02 / h2/2.5/ h2o/12/ co/1.9/ co2/3.8/ h2o2+oh = h2o+ho2 1.000E+12 0.00 0.000E+00 rev / 1.685E+11 0.33 3.146E+04 / DUPLICATE c2h4+o = ch3+hco 1.020E+07 1.88 1.790E+02 rev / 2.851E+08 1.05 3.177E+04 / h+c2h4(+m) = c2h5(+m) 1.081E+12 0.45 1.822E+03 low/1.112E+34 -5.000E+00 4.448E+03/ troe/1.0 1.000E-15 9.500E+01 2.000E+02/ h2/2/ h2o/5/ co/2/ co2/3/ ch3oh(+m) = ch3+oh(+m) 1.900E+16 0.00 9.173E+04 low / 2.95E+44 -7.35 9.546E+04/ troe/0.414 279. 5459./ h2/2/ h2o/16/ co/2/ co2/3/ c2h6+h = c2h5+h2 5.540E+02 3.50 5.167E+03 rev / 1.355E-01 4.06 8.857E+03 / ch3oh+ho2 = ch2oh+h2o2 3.980E+13 0.00 1.940E+04 rev / 3.130E+15 -0.90 1.075E+04 / c2h5+o2 = c2h4+ho2 1.220E+30 -5.76 1.010E+04 rev / 1.259E+30 -5.63 2.231E+04 / c2h6+oh = c2h5+h2o 5.125E+06 2.06 8.550E+02 rev / 1.010E+07 2.06 2.298E+04 / c2h6+o = c2h5+oh 1.130E+14 0.00 7.850E+03 rev / 2.080E+13 0.00 1.272E+04 / ch3+ho2 = ch3o+oh 1.100E+13 0.00 0.000E+00 rev / 4.780E+14 -0.35 2.455E+04 / co+ho2 = co2+oh 3.010E+13 0.00 2.300E+04 rev / 6.435E+15 -0.33 8.461E+04 / ch3+ch3(+m) = c2h6(+m) 9.214E+16 -1.17 6.358E+02 low/1.135E+36 -5.246 1.705E+03/ troe/0.405 1120. 69.6 1.e+15/ h2/2/ h2o/5/ co/2/ co2/3/ h2o+m = h+oh+m 1.837E+27 -3.00 1.226E+05 rev/ 2.250E+22 -2.00 0.000E+00 / h2/2.5/ h2o/12/ co/1.9/ co2/3.8/ h+o2(+m) = ho2(+m) 1.475E+12 0.60 0.000E+00 low/3.500e+16 -4.10E-01 -1.1160E+03 / troe/5.0000E-01 1.0000E-30 1.0000E+30/ h2/2.5/ h2o/12/ co/1.9/ co2/3.8/ co+o(+m) = co2(+m) 1.800E+10 0.00 2.384E+03 low/1.350E+24 -2.788 4191./ h2/2.5/ h2o/12/ co/1.9/ co2/3.8/ co+o2 = co2+o 1.068E-15 7.13 1.332E+04 rev / 9.444E-15 7.13 1.954E+04 / hco+h = co+h2 7.340E+13 0.00 0.000E+00 rev / 4.813E+14 0.00 9.000E+04 / hco+o = co+oh 3.020E+13 0.00 0.000E+00 rev / 8.697E+13 0.00 8.790E+04 / ch2o+m = hco+h+m 6.283E+29 -3.57 9.320E+04 rev / 2.660E+24 -2.57 4.270E+02 / ch2o+oh = hco+h2o 3.430E+09 1.18 -4.470E+02 rev / 1.186E+09 1.18 2.938E+04 / ch2o+h = hco+h2 9.334E+08 1.50 2.976E+03 rev / 7.453E+07 1.50 1.765E+04 / ch2o+o = hco+oh 6.260E+09 1.15 2.260E+03 rev / 2.195E+08 1.15 1.484E+04 / ch3+oh = ch2o+h2 2.250E+13 0.00 4.300E+03 rev / 6.756E+14 0.00 7.603E+04 / ch3+o = ch2o+h 8.000E+13 0.00 0.000E+00 rev / 1.055E+15 0.00 6.963E+04 / ch3+o2 = ch3o+o 1.995E+18 -1.57 2.923E+04 rev / 3.585E+18 -1.59 -1.610E+03 / ch2o+ch3 = hco+ch4 3.636E-06 5.42 9.980E+02 rev / 7.584E-06 5.42 1.615E+04 / hco+ch3 = ch4+co 1.210E+14 0.00 0.000E+00 rev / 2.073E+16 0.00 9.048E+04 / ch3o(+m) = ch2o+h(+m) 5.450E+13 0.00 1.350E+04 low /2.344E+25 -2.7 3.060E+04/ c2h4(+m) = c2h2+h2(+m) 1.800E+13 0.00 7.600E+04 low /1.500E+15 0.0 5.5443E+04/ ho2+o = oh+o2 3.250E+13 0.00 0.000E+00 rev / 7.857E+14 -0.33 5.539E+04 / hco+ho2 = ch2o+o2 2.974E+10 0.33 -3.861E+03 rev / 2.050E+13 0.00 3.895E+04 / ch3o+o2 = ch2o+ho2 5.500E+10 0.00 2.424E+03 rev / 1.318E+09 0.35 3.139E+04 / ch3+ho2 = ch4+o2 3.000E+12 0.00 0.000E+00 rev / 4.314E+15 -0.33 5.796E+04 / hco+o2 = co+ho2 7.580E+12 0.00 4.100E+02 rev / 9.029E+11 0.33 3.293E+04 / ho2+h = oh+oh 7.080E+13 0.00 3.000E+02 rev / 1.352E+14 -0.33 3.957E+04 / ho2+h = h2+o2 1.660E+13 0.00 8.200E+02 rev / 9.138E+14 -0.33 5.830E+04 / ho2+oh = h2o+o2 2.890E+13 0.00 -5.000E+02 rev/ 6.888E+15 -0.33 7.214E+04 / h2o2+o2 = ho2+ho2 5.942E+17 -0.66 5.315E+04 rev/ 4.200E+14 0.00 1.198E+04 / DUPLICATE oh+oh(+m) = h2o2(+m) 1.236E+14 -.37 0.000E+00 low /3.041E+30 -4.63 2049./ troe /0.47 100. 2000. 1.0e+15/ h2/2.5/ h2o/12/ co/1.9/ co2/3.8/ h2o2+h = h2o+oh 2.410E+13 0.00 3.970E+03 rev / 7.750E+12 0.00 7.471E+04 / ch4+ho2 = ch3+h2o2 3.420E+11 0.00 1.929E+04 rev / 3.365E+11 -0.33 2.502E+03 / ch2o+ho2 = hco+h2o2 5.820E-03 4.53 6.557E+03 rev / 1.194E-02 4.20 4.921E+03 / oh+m = o+h+m 3.909E+22 -2.00 1.053E+05 rev / 4.720E+18 -1.00 0.000E+00 / h2/2.5/ h2o/12/ co/1.9/ co2/3.8/ o2+m = o+o+m 6.473E+20 -1.50 1.215E+05 rev/ 6.170E+15 -0.50 0.000E+00 / h2/2.5/ h2o/12/ co/1.9/ co2/3.8/ h2+m = h+h+m 4.570E+19 -1.40 1.044E+05 rev/ 2.423E+15 -0.40 -3.040E+03 / h2/2.5/ h2o/12/ co/1.9/ co2/3.8/ c2h3+h(+m) = c2h4(+m) 6.100E+12 0.27 2.800E+02 low /9.800E+29 -3.86 3.320E+03/ troe /0.782 208. 2663. 6095./ h2/2.5/ h2o/12/ co/1.9/ co2/3.8/ c2h5+c2h3 = c2h4+c2h4 3.000E+12 0.00 0.000E+00 rev/ 4.820E+14 0.00 7.153E+04 / c2h2+h(+m) = c2h3(+m) 3.110E+11 0.58 2.589E+03 low/2.254e40 -7.269 6577./ troe/ 1.0 1.e-15 675. 1.e+15/ h2/2/ h2o/5/ co/2/ co2/3/ c2h4+h = c2h3+h2 8.420E-03 4.62 2.583E+03 rev / 5.723E-01 3.79 3.233E+03 / c2h4+oh = c2h3+h2o 2.050E+13 0.00 5.955E+03 rev / 1.200E+12 0.00 1.400E+04 / c2h3+o2 = c2h2+ho2 5.190E-15 -1.26 3.310E+03 rev / 2.727E-16 -0.93 1.140E+04 / DUPLICATE c2h2+m = c2h+h+m 4.200E+16 0.00 1.070E+05 rev / 7.130E+07 2.08 -2.891E+04 / c2h2+o2 = hcco+oh 2.000E+08 1.50 3.010E+04 rev / 2.232E+05 1.50 2.540E+04 / ch2+o2 = co+h2o 7.280E+19 -2.54 1.809E+03 rev / 8.508E+20 -2.54 1.798E+05 / c2h2+oh = c2h+h2o 3.370E+07 2.00 1.400E+04 rev / 4.671E+03 3.08 6.850E+02 / o+c2h2 = c2h+oh 3.160E+15 -0.60 1.500E+04 rev / 4.443E+10 0.48 -1.557E+04 / c2h2+o = ch2+co 6.120E+06 2.00 1.900E+03 rev / 1.152E+06 2.00 5.257E+04 / c2h+o2 = hco+co 2.410E+12 0.00 0.000E+00 rev / 1.328E+16 -1.08 1.541E+05 / c2h+o = co+ch 1.810E+13 0.00 0.000E+00 rev / 7.478E+16 -1.08 8.213E+04 / ch2+o2 = hco+oh 1.290E+20 -3.30 2.840E+02 rev / 5.310E+19 -3.30 7.317E+04 / ch2+o = co+h+h 5.000E+13 0.00 0.000E+00 rev / 0.000E+00 0.00 0.000E+00 / ch2+h = ch+h2 1.000E+18 -1.56 0.000E+00 rev / 7.026E+17 -1.56 2.990E+03 / ch2+oh = ch+h2o 1.130E+07 2.00 3.000E+03 rev / 3.437E+07 2.00 2.115E+04 / ch2+o2 = co2+h+h 3.290E+21 -3.30 2.868E+03 rev / 0.000E+00 0.00 0.000E+00 / ch+o2 = hco+o 3.300E+13 0.00 0.000E+00 rev / 4.402E+13 0.00 7.199E+04 / ch3oh+oh = ch2oh+h2o 7.100E+06 1.80 -5.960E+02 rev / 3.293E+01 3.46 2.272E+04 / ch3oh+h = ch3o+h2 3.600E+12 0.00 6.095E+03 rev / 7.467E+12 -0.02 7.825E+03 / ch3oh+h = ch2oh+h2 1.440E+13 0.00 6.095E+03 rev / 1.543E+07 1.66 1.425E+04 / ch3oh+ch3 = ch2oh+ch4 3.190E+01 3.17 7.172E+03 rev / 8.927E-04 4.83 1.581E+04 / ch3oh+o = ch2oh+oh 3.880E+05 2.50 3.080E+03 rev / 4.960E+03 2.50 8.781E+03 / ch2oh+o2 = ch2o+ho2 3.810E+06 2.00 1.641E+03 rev / 1.768E+11 0.67 2.418E+04 / ch2oh(+m) = ch2o+h(+m) 2.800E+14 -0.73 3.282E+04 low/6.01E+33 -5.39 3.62E+04/ troe/ 0.96 67.6 1855. 7543./ c2h3+o2 = c2h2+ho2 2.120E-06 6.00 9.484E+03 rev / 1.114E-07 6.33 1.757E+04 / DUPLICATE h2o2+o = oh+ho2 9.550E+06 2.00 3.970E+03 rev / 2.541E+07 1.68 1.985E+04 / c2h2+o = hcco+h 1.430E+07 2.00 1.900E+03 rev / 2.021E+05 2.00 1.331E+04 / c2h2+oh = ch2co+h 3.236E+13 0.00 1.200E+04 rev / 3.194E+14 0.00 3.267E+04 / ch2co+h = ch3+co 1.100E+13 0.00 3.400E+03 rev / 2.400E+12 0.00 4.020E+04 / ch2co+o = ch2+co2 1.750E+12 0.00 1.350E+03 rev / 3.739E+12 0.00 5.369E+04 / ch2+o2 = ch2o+o 3.290E+21 -3.30 2.868E+03 rev / 3.862E+22 -3.30 6.318E+04 / ch2co(+m) = ch2+co(+m) 3.000E+14 0.00 7.098E+04 low/3.6000E+15 0.00 5.9270E+04/ ch2co+o = hcco+oh 1.000E+13 0.00 8.000E+03 rev / 1.432E+10 0.00 -1.255E+03 / ch2co+oh = hcco+h2o 1.000E+13 0.00 2.000E+03 rev / 1.412E+11 0.00 9.995E+03 / ch2co+h = hcco+h2 2.000E+14 0.00 8.000E+03 rev / 6.522E+11 0.00 8.400E+02 / hcco+oh = hco+hco 1.000E+13 0.00 0.000E+00 rev / 4.820E+13 0.00 4.036E+04 / hcco+h = ch2(s)+co 1.100E+14 0.00 0.000E+00 rev / 6.660E+13 0.00 3.926E+04 / hcco+o = h+co+co 8.000E+13 0.00 0.000E+00 rev / 0.000E+00 0.00 0.000E+00 / c2h6+o2 = c2h5+ho2 4.000E+13 0.00 5.090E+04 rev / 3.000E+11 0.00 0.000E+00 / c2h6+ho2 = c2h5+h2o2 1.700E+13 0.00 2.046E+04 rev / 2.500E+11 0.00 6.500E+03 / ch2+o2 = co2+h2 1.010E+21 -3.30 1.508E+03 rev / 3.054E+23 -3.30 1.867E+05 / ch3+c2h3 = ch4+c2h2 3.920E+11 0.00 0.000E+00 rev / 2.962E+13 0.00 6.605E+04 / ch3+c2h5 = ch4+c2h4 1.950E+13 -0.50 0.000E+00 rev / 2.895E+16 -0.70 7.017E+04 / ch3oh+ch2o = ch3o+ch3o 3.835E+13 0.05 8.472E+04 rev / 6.030E+13 0.00 0.000E+00 / ch2o+ch3o = ch3oh+hco 1.150E+11 0.00 1.280E+03 rev / 3.020E+11 0.00 1.816E+04 / ch4+ch3o = ch3+ch3oh 1.570E+11 0.00 8.842E+03 rev / 1.046E+09 0.00 5.000E+04 / c2h6+ch3o = c2h5+ch3oh 3.000E+11 0.00 7.000E+03 rev / 1.714E+10 0.00 5.000E+04 / c2h3+h = c2h2+h2 2.000E+13 0.00 2.500E+03 rev / 1.331E+13 0.00 6.808E+04 / ch3o+ch3oh = ch2oh+ch3oh 3.000E+11 0.00 4.074E+03 rev / 1.549E+05 1.68 1.050E+04 / ch3oh+oh = ch3o+h2o 1.000E+06 2.10 4.967E+02 rev / 8.981E+06 2.08 1.738E+04 / c2h5+h = ch3+ch3 3.610E+13 0.00 0.000E+00 rev / 5.446E+16 -1.03 1.698E+04 / c2h3+o2 = ch2o+hco 1.700E+29 -5.31 6.500E+03 rev / 1.657E+29 -5.31 9.305E+04 / c2h6 = c2h5+h 2.783E+21 -1.56 1.038E+05 rev / 3.610E+13 0.00 0.000E+00 / c2h5oh(+m) = ch2oh+ch3(+m) 5.710E+23 -1.68 9.441E+04 low/3.110E+85 -18.84 1.1310E+05/ troe/ 0.5 550. 825. 6100./ h2/2/ h2o/5/ co/2/ co2/3/ c2h5oh(+m) = c2h5+oh(+m) 2.400E+23 -1.62 9.954E+04 low/5.110E+85 -18.80 1.1877E+05/ troe/ 0.5 650. 800. 1.0E+15/ h2/2/ h2o/5/ co/2/ co2/3/ c2h5oh(+m) = c2h4+h2o(+m) 2.790E+13 0.09 6.614E+04 low/2.570E+83 -18.85 8.6453E+04/ troe/ 0.7 350. 800. 3800./ h2o/5/ c2h5oh(+m) = ch3cho+h2(+m) 7.240E+11 0.10 9.101E+04 low/4.460E+87 -19.42 1.1559E+05/ troe/ 0.9 900. 1100. 3500./ h2o/5/ c2h5oh+o2 = pc2h4oh+ho2 2.000E+13 0.00 5.280E+04 rev / 3.470E+08 0.32 -1.105E+03 / c2h5oh+o2 = sc2h4oh+ho2 1.500E+13 0.00 5.015E+04 rev / 1.079E+09 0.63 -5.040E+02 / c2h5oh+oh = pc2h4oh+h2o 1.740E+11 0.27 6.000E+02 rev / 7.196E+08 0.26 1.933E+04 / c2h5oh+oh = sc2h4oh+h2o 4.640E+11 0.15 0.000E+00 rev / 7.957E+09 0.45 2.199E+04 / c2h5oh+h = pc2h4oh+h2 1.230E+07 1.80 5.098E+03 rev / 1.175E+04 1.79 8.677E+03 / c2h5oh+h = sc2h4oh+h2 2.580E+07 1.65 2.827E+03 rev / 1.022E+05 1.95 9.657E+03 / c2h5oh+ho2 = pc2h4oh+h2o2 1.230E+04 2.55 1.575E+04 rev / 3.019E+02 2.21 3.021E+03 / c2h5oh+ho2 = sc2h4oh+h2o2 8.200E+03 2.55 1.075E+04 rev / 8.348E+02 2.53 1.272E+03 / c2h5oh+ho2 = c2h5o+h2o2 2.500E+12 0.00 2.400E+04 rev / 1.514E+14 -1.80 3.800E+04 / c2h5oh+o = pc2h4oh+oh 9.410E+07 1.70 5.459E+03 rev / 3.947E+04 1.69 6.943E+03 / c2h5oh+o = sc2h4oh+oh 1.880E+07 1.85 1.824E+03 rev / 3.270E+04 2.15 6.559E+03 / c2h5oh+ch3 = pc2h4oh+ch4 1.330E+02 3.18 9.362E+03 rev / 3.319E+00 3.17 1.342E+04 / c2h5oh+ch3 = sc2h4oh+ch4 4.440E+02 2.90 7.690E+03 rev / 4.594E+01 3.20 1.500E+04 / c2h5oh+c2h5 = pc2h4oh+c2h6 5.000E+10 0.00 1.340E+04 rev / 6.995E+10 0.00 2.699E+04 / c2h5oh+c2h5 = sc2h4oh+c2h6 5.000E+10 0.00 1.040E+04 rev / 6.995E+10 0.00 2.399E+00 / pc2h4oh = c2h4+oh 1.293E+12 -0.37 2.685E+04 rev / 9.930E+11 0.00 -9.600E+02 / sc2h4oh+m = ch3cho+h+m 1.000E+14 0.00 2.500E+04 rev / 8.166E+12 0.37 7.300E+02 / c2h4+ch3 = c2h3+ch4 6.620E+00 3.70 9.500E+03 rev / 1.440E+00 4.02 5.472E+03 / ch3co(+m) = ch3+co(+m) 3.000E+12 0.00 1.672E+04 low/1.20E+15 0.00 1.2518E+04/ ch3cho = ch3+hco 2.614E+15 0.15 8.055E+04 rev / 2.000E+13 0.00 0.000E+00 / ch3cho+o2 = ch3co+ho2 3.010E+13 0.00 3.915E+04 rev / 8.552E+10 0.32 -1.940E+03 / ch3cho+oh = ch3co+h2o 2.000E+06 1.80 1.300E+03 rev / 1.354E+06 1.79 3.285E+04 / ch3cho+h = ch3co+h2 1.340E+13 0.00 3.300E+03 rev / 2.096E+12 -0.01 1.969E+04 / ch3cho+o = ch3co+oh 5.940E+12 0.00 1.868E+03 rev / 4.080E+11 -0.01 1.617E+04 / ch3cho+ho2 = ch3co+h2o2 3.010E+12 0.00 1.193E+04 rev / 1.210E+13 -0.34 1.201E+04 / ch3cho+ch3 = ch3co+ch4 2.608E+06 1.78 5.911E+03 rev / 1.066E+07 1.77 2.279E+04 / c2h4+o2 = c2h3+ho2 4.000E+13 0.00 5.820E+04 rev / 4.939E+13 -0.50 1.368E+03 / ch2o+m = co+h2+m 1.826E+32 -4.42 8.712E+04 rev / 5.070E+27 -3.42 8.435E+04 / c2h4+ch3o = c2h3+ch3oh 1.200E+11 0.00 6.750E+03 rev / 1.000E+10 0.00 9.000E+03 / ch3coch3 = ch3co+ch3 1.219E+23 -1.99 8.395E+04 rev / 1.000E+13 0.00 0.000E+00 / ch3coch3+oh = ch3coch2+h2o 1.054E+10 0.97 1.586E+03 rev / 6.931E+09 0.97 2.325E+04 / ch3coch3+h = ch3coch2+h2 5.628E+07 2.00 7.700E+03 rev / 9.000E+12 0.00 1.450E+05 / ch3coch3+o = ch3coch2+oh 1.130E+14 0.00 7.850E+03 rev / 7.500E+12 0.00 1.230E+04 / ch3coch3+ch3 = ch3coch2+ch4 3.960E+11 0.00 9.784E+03 rev / 5.378E+08 0.86 1.754E+04 / ch3coch3+ch3o = ch3coch2+ch3oh 1.000E+11 0.00 7.000E+03 rev / 1.000E+10 0.00 9.000E+03 / ch3coch2 = ch2co+ch3 1.000E+14 0.00 3.100E+04 rev / 1.000E+11 0.00 6.000E+03 / ch3coch3+o2 = ch3coch2+ho2 1.200E+14 0.00 4.600E+04 rev / 2.000E+12 0.00 2.000E+03 / ch3coch3+ho2 = ch3coch2+h2o2 1.700E+13 0.00 2.046E+04 rev / 1.000E+11 0.00 8.000E+03 / c2h5co = c2h5+co 1.834E+15 -0.73 1.291E+04 rev / 1.510E+11 0.00 4.810E+03 / c2h5cho+h = c2h5co+h2 3.980E+13 0.00 4.200E+03 rev / 1.778E+13 0.00 2.367E+04 / c2h5cho+o = c2h5co+oh 5.010E+12 0.00 1.790E+03 rev / 1.000E+12 0.00 1.916E+04 / c2h5cho+oh = c2h5co+h2o 9.240E+06 1.50 -9.620E+02 rev / 5.855E+06 1.50 3.058E+04 / c2h5cho+ch3 = c2h5co+ch4 2.608E+06 1.78 5.911E+03 rev / 9.972E+06 1.78 2.278E+04 / c2h5cho+ho2 = c2h5co+h2o2 1.000E+12 0.00 1.100E+04 rev / 1.000E+12 0.00 1.400E+04 / c2h5cho+ch3o = c2h5co+ch3oh 1.000E+12 0.00 3.300E+03 rev / 3.160E+11 0.00 1.800E+04 / c2h5cho+c2h5 = c2h5co+c2h6 1.000E+12 0.00 8.000E+03 rev / 1.585E+13 0.00 2.800E+04 / c2h5cho = c2h5+hco 9.850E+18 -0.73 8.171E+04 rev / 1.810E+13 0.00 0.000E+00 / c2h5cho+o2 = c2h5co+ho2 2.000E+13 0.50 4.220E+04 rev / 1.909E+14 0.50 3.090E+03 / c2h5cho+c2h3 = c2h5co+c2h4 1.700E+12 0.00 8.440E+03 rev / 2.488E+14 0.00 2.619E+04 / h2o2+h = h2+ho2 4.820E+13 0.00 7.950E+03 rev / 1.875E+12 0.33 2.426E+04 / hco+o = co2+h 3.000E+13 0.00 0.000E+00 rev / 9.677E+15 0.00 1.102E+05 / ch3+m = ch2+h+m 1.968E+16 0.00 9.252E+04 rev / 2.107E+11 1.00 -1.962E+04 / ch3+h = ch2+h2 9.000E+13 0.00 1.510E+04 rev / 1.818E+13 0.00 1.040E+04 / ch3+oh = ch2+h2o 3.000E+06 2.00 2.500E+03 rev / 2.623E+06 2.00 1.296E+04 / ch+ch4 = c2h4+h 6.000E+13 0.00 0.000E+00 rev / 3.573E+14 0.00 5.548E+04 / ch3oh(+m) = ch2oh+h(+m) 2.690E+16 -0.08 9.894E+04 low / 2.34E+40 -6.33 1.031E+05/ troe/ 0.773 693. 5333./ ch3co+h = ch2co+h2 2.000E+13 0.00 1.000E-10 rev / 7.270E+09 0.00 8.304E+04 / ch3co+o = ch2co+oh 2.000E+13 0.00 1.000E-10 rev / 7.270E+09 0.00 8.304E+04 / ch3co+ch3 = ch2co+ch4 5.000E+13 0.00 1.000E-10 rev / 7.270E+09 0.00 8.304E+04 / c2h4+o = ch2cho+h 3.390E+06 1.88 1.790E+02 rev / 9.481E+06 1.79 1.605E+04 / c2h5+o = ch3cho+h 5.000E+13 0.00 0.000E+00 rev / 9.000E+13 0.00 7.268E+04 / c2h6+ch = c2h5+ch2 1.100E+14 0.00 -2.600E+02 rev / 3.829E+10 0.56 4.400E+02 / ch2oh+ch2o=ch3oh+hco 1.292E-01 4.56 6.596E+03 rev / 9.630E+03 2.90 1.311E+04 / c2h5oh+oh = c2h5o+h2o 7.460E+11 0.30 1.634E+03 rev / 3.956E+13 -0.14 1.852E+04 / c2h5oh+h = c2h5o+h2 1.500E+07 1.60 3.038E+03 rev / 1.837E+08 1.17 4.772E+03 / c2h5oh+o = c2h5o+oh 1.580E+07 2.00 4.448E+03 rev / 8.500E+07 1.56 4.087E+03 / c2h5oh+ch3 = c2h5o+ch4 1.340E+02 2.92 7.452E+03 rev / 4.288E+04 2.48 9.666E+03 / sc2h4oh+o2 = ch3cho+ho2 3.810E+06 2.00 1.641E+03 rev / 1.066E+08 1.70 2.733E+04 / c2h5o+o2 = ch3cho+ho2 4.280E+10 0.00 1.097E+03 rev / 3.872E+08 0.44 3.188E+04 / h2o2+o2 = ho2+ho2 1.839E+14 -0.66 3.955E+04 rev / 1.300E+11 0.00 -1.629E+03 / DUPLICATE h2o2+oh = h2o+ho2 5.800E+14 0.00 9.560E+03 rev / 9.771E+13 0.33 4.102E+04 / DUPLICATE c2h5o2 = c2h5+o2 4.930E+50 -11.50 4.225E+04 rev / 1.090E+48 -11.54 1.022E+04 / ch3o2+m = ch3+o2+m 4.343E+27 -3.42 3.047E+04 rev / 5.440E+25 -3.30 0.000E+00 / ch3o2h = ch3o+oh 6.310E+14 0.00 4.230E+04 rev / 1.166E+11 0.60 -1.771E+03 / c2h5o2h = c2h5o+oh 6.310E+14 0.00 4.230E+04 rev / 1.012E+08 1.48 -3.887E+03 / c2h5o+m = ch3+ch2o+m 1.350E+38 -6.96 2.380E+04 rev / 6.442E+36 -6.99 1.685E+04 / ch3o2+ch2o = ch3o2h+hco 1.990E+12 0.00 1.167E+04 rev / 8.504E+12 -0.50 7.009E+03 / c2h5o2+ch2o = c2h5o2h+hco 1.990E+12 0.00 1.167E+04 rev / 6.411E+12 -0.47 6.967E+03 / c2h4+ch3o2 = c2h3+ch3o2h 1.130E+13 0.00 3.043E+04 rev / 3.000E+12 0.00 1.150E+04 / c2h4+c2h5o2 = c2h3+c2h5o2h 1.130E+13 0.00 3.043E+04 rev / 3.000E+12 0.00 1.150E+04 / ch4+ch3o2 = ch3+ch3o2h 1.810E+11 0.00 1.848E+04 rev / 3.708E+11 -0.50 -1.327E+03 / ch4+c2h5o2 = ch3+c2h5o2h 1.810E+11 0.00 1.848E+04 rev / 2.796E+11 -0.47 -1.369E+03 / ch3oh+ch3o2 = ch2oh+ch3o2h 1.810E+12 0.00 1.371E+04 rev / 1.038E+08 1.16 2.542E+03 / ch3oh+c2h5o2 = ch2oh+c2h5o2h 1.810E+12 0.00 1.371E+04 rev / 7.824E+07 1.19 2.500E+03 / c2h5+ho2 = c2h5o+oh 3.200E+13 0.00 0.000E+00 rev / 3.075E+15 -0.32 2.749E+04 / ch3o2+ch3 = ch3o+ch3o 7.000E+12 0.00 -1.000E+03 rev / 2.971E+16 -0.93 2.831E+04 / ch3o2+c2h5 = ch3o+c2h5o 7.000E+12 0.00 -1.000E+03 rev / 6.569E+16 -0.90 3.126E+04 / ch3o2+ho2 = ch3o2h+o2 1.750E+10 0.00 -3.275E+03 rev / 5.156E+13 -0.83 3.488E+04 / ch3oh+o2 = ch2oh+ho2 2.050E+13 0.00 4.490E+04 rev / 3.989E+05 1.99 -4.424E+03 / c2h5o2+ho2 = c2h5o2h+o2 1.750E+10 0.00 -3.275E+03 rev / 3.887E+13 -0.79 3.484E+04 / ch3o2+ch3o2 = ch2o+ch3oh+o2 3.110E+14 -1.61 -1.051E+03 rev / 0.000E+00 0.00 0.000E+00 / ch3o2+ch3o2 = o2+ch3o+ch3o 1.400E+16 -1.61 1.860E+03 rev / 0.000E+00 0.00 0.000E+00 / c2h6+ch3o2 = c2h5+ch3o2h 1.700E+13 0.00 2.046E+04 rev / 7.500E+11 0.00 1.280E+03 / c2h6+c2h5o2 = c2h5+c2h5o2h 1.700E+13 0.00 2.046E+04 rev / 7.500E+11 0.00 1.280E+03 / o2c2h4oh = pc2h4oh+o2 3.900E+16 -1.00 3.000E+04 rev / 1.200E+11 0.00 -1.100E+03 / o2c2h4oh = oh+ch2o+ch2o 1.250E+10 0.00 1.890E+04 rev / 0.000E+00 0.00 0.000E+00 / c2h5o2 = c2h4o2h 5.640E+47 -11.44 3.732E+04 rev / 6.990E+48 -12.22 2.585E+04 / c2h4o2h = c2h4o1-2+oh 4.250E+22 -4.18 2.235E+04 rev / 0.000E+00 0.00 0.000E+00 / ch3co3 = ch3co+o2 4.732E+19 -1.93 2.590E+04 rev / 1.200E+11 0.00 -1.100E+03 / ch3co2+m = ch3+co2+m 4.400E+15 0.00 1.050E+04 rev / 1.000E-10 0.00 0.000E+00 / ch3co3h = ch3co2+oh 5.010E+14 0.00 4.015E+04 rev / 1.738E+08 1.57 1.305E+03 / ch3co3+ho2 = ch3co3h+o2 1.750E+10 0.00 -3.275E+03 rev / 4.000E+12 -0.30 5.270E+04 / c2h5o+m = ch3cho+h+m 1.160E+35 -5.89 2.527E+04 rev / 3.063E+30 -4.78 6.100E+03 / h2o2+ch3co3 = ho2+ch3co3h 2.410E+12 0.00 9.936E+03 rev / 3.894E+11 0.35 2.473E+04 / ch4+ch3co3 = ch3+ch3co3h 1.810E+11 0.00 1.848E+04 rev / 2.877E+10 0.03 1.649E+04 / c2h4+ch3co3 = c2h3+ch3co3h 1.130E+13 0.00 3.043E+04 rev / 3.189E+15 -0.80 2.957E+04 / c2h6+ch3co3 = c2h5+ch3co3h 1.700E+13 0.00 2.046E+04 rev / 1.727E+10 0.59 2.264E+04 / ch2o+ch3co3 = hco+ch3co3h 1.990E+12 0.00 1.167E+04 rev / 6.598E+11 0.03 2.483E+04 / ch3o2+ch3cho = ch3o2h+ch3co 3.010E+12 0.00 1.193E+04 rev / 2.519E+13 -0.51 8.991E+03 / ch3cho+ch3co3 = ch3co+ch3co3h 3.010E+12 0.00 1.193E+04 rev / 1.955E+12 0.02 2.681E+04 / c2h3co = c2h3+co 2.040E+14 -0.40 3.145E+04 rev / 1.510E+11 0.00 4.810E+03 / c2h3cho+oh = c2h3co+h2o 9.240E+06 1.50 -9.620E+02 rev / 1.439E+07 1.53 3.645E+04 / c2h3cho+h = c2h3co+h2 1.340E+13 0.00 3.300E+03 rev / 4.820E+12 0.03 2.556E+04 / c2h3cho+o = c2h3co+oh 5.940E+12 0.00 1.868E+03 rev / 9.384E+11 0.03 2.203E+04 / c2h3cho+ho2 = c2h3co+h2o2 3.010E+12 0.00 1.193E+04 rev / 2.783E+13 -0.30 1.788E+04 / c2h3cho+ch3 = c2h3co+ch4 2.608E+06 1.78 5.911E+03 rev / 2.451E+07 1.81 2.865E+04 / c2h3cho+ch3o2 = c2h3co+ch3o2h 3.010E+12 0.00 1.193E+04 rev / 5.794E+13 -0.48 1.486E+04 / c2h4o2h = c2h4+ho2 9.290E+30 -6.10 1.993E+04 rev / 1.879E+25 -4.48 1.166E+04 / c2h4+ch3o2 = c2h4o1-2+ch3o 2.820E+12 0.00 1.711E+04 rev / 0.000E+00 0.00 0.000E+00 / c2h4+c2h5o2 = c2h4o1-2+c2h5o 2.820E+12 0.00 1.711E+04 rev / 0.000E+00 0.00 0.000E+00 / c2h4o1-2 = ch3+hco 3.630E+13 0.00 5.720E+04 rev / 1.482E+06 1.00 2.420E+02 / c2h4o1-2 = ch3cho 7.407E+12 0.00 5.380E+04 rev / 3.953E+07 1.15 7.739E+04 / c2h4o1-2+oh = c2h3o1-2+h2o 1.780E+13 0.00 3.610E+03 rev / 4.815E+12 -0.98 3.923E+04 / c2h4o1-2+h = c2h3o1-2+h2 8.000E+13 0.00 9.680E+03 rev / 4.998E+12 -0.98 3.014E+04 / c2h4o1-2+ho2 = c2h3o1-2+h2o2 1.130E+13 0.00 3.043E+04 rev / 1.814E+13 -1.30 3.458E+04 / c2h4o1-2+ch3o2 = c2h3o1-2+ch3o2h 1.130E+13 0.00 3.043E+04 rev / 3.778E+13 -1.48 3.156E+04 / c2h4o1-2+c2h5o2 = c2h3o1-2+c2h5o2h 1.130E+13 0.00 3.043E+04 rev / 2.849E+13 -1.44 3.152E+04 / c2h4o1-2+ch3 = c2h3o1-2+ch4 1.070E+12 0.00 1.183E+04 rev / 1.746E+12 -0.98 3.277E+04 / c2h4o1-2+ch3o = c2h3o1-2+ch3oh 1.200E+11 0.00 6.750E+03 rev / 3.614E+09 -0.95 2.548E+04 / ch3coch2o2 = ch3coch2+o2 8.093E+15 -1.11 2.745E+04 rev / 1.200E+11 0.00 -1.100E+03 / ch3coch3+ch3coch2o2 = ch3coch2+ch3coch2o2h 1.000E+11 0.00 5.000E+03 rev / 1.995E+10 0.00 1.000E+04 / ch2o+ch3coch2o2 = hco+ch3coch2o2h 1.288E+11 0.00 9.000E+03 rev / 2.512E+10 0.00 1.010E+04 / ho2+ch3coch2o2 = ch3coch2o2h+o2 1.000E+12 0.00 0.000E+00 rev / 0.000E+00 0.00 0.000E+00 / ch3coch2o2h = ch3coch2o+oh 1.000E+16 0.00 4.300E+04 rev / 9.732E+08 1.70 -4.175E+03 / ch3coch2o = ch3co+ch2o 4.159E+16 -1.03 1.396E+04 rev / 1.000E+11 0.00 1.190E+04 / c2h5cho+ch3o2 = c2h5co+ch3o2h 3.010E+12 0.00 1.193E+04 rev / 2.358E+13 -0.51 8.983E+03 / c2h5cho+c2h5o = c2h5co+c2h5oh 6.026E+11 0.00 3.300E+03 rev / 3.020E+11 0.00 1.816E+04 / c2h5cho+c2h5o2 = c2h5co+c2h5o2h 3.010E+12 0.00 1.193E+04 rev / 1.778E+13 -0.47 8.941E+03 / c2h5cho+ch3co3 = c2h5co+ch3co3h 3.010E+12 0.00 1.193E+04 rev / 1.829E+12 0.02 2.680E+04 / ch3cho+oh = ch3 + hco2h 3.000E+15 -1.08 0.000E+00 rev / 5.350E+19 -1.68 1.198E+05 / c2h3o1-2 = ch3co 8.500E+14 0.00 1.400E+04 rev / 1.136E+10 2.11 3.352E+04 / c2h3o1-2 = ch2cho 1.000E+14 0.00 1.400E+04 rev / 1.233E+11 1.71 2.830E+04 / ch2cho = ch2co+h 3.094E+15 -0.26 5.082E+04 rev / 5.000E+13 0.00 1.230E+04 / ch2cho+o2 = ch2o+co+oh 2.000E+13 0.00 4.200E+03 rev / 0.000E+00 0.00 0.000E+00 / hco3 = hco+o2 7.766E+26 -3.96 4.423E+04 rev / 1.200E+11 0.00 -1.100E+03 / ch2o+hco3 = hco+hco3h 1.990E+12 0.00 1.167E+04 rev / 2.331E+02 2.30 4.687E+03 / hco3h = hco2+oh 5.010E+14 0.00 4.015E+04 rev / 2.322E+06 2.15 6.550E+02 / hco2+m = h+co2+m 2.443E+15 -0.50 2.650E+04 rev / 7.500E+13 0.00 2.900E+04 / hcco+o2 = co2+hco 2.400E+11 0.00 -8.540E+02 rev / 1.474E+14 0.00 1.336E+05 / ch3cho+oh = ch2cho + h2o 1.720E+05 2.40 8.150E+02 rev / 6.181E+08 1.25 8.984E+04 / ch2co+oh = ch2oh+co 3.730E+12 0.00 -1.013E+03 rev / 9.430E+06 1.66 2.749E+04 / ch3+o2 = ch2o+oh 7.470E+11 0.00 1.425E+04 rev / 7.778E+11 0.00 6.777E+04 / c2h4+h2 = ch3+ch3 3.767E+12 0.83 8.471E+04 rev / 1.000E+14 0.00 3.200E+04 / ch3+oh = ch2(s)+h2o 2.650E+13 0.00 2.186E+03 rev / 3.236E+10 0.89 1.211E+03 / c2h4+ho2 = c2h4o1-2+oh 2.230E+12 0.00 1.719E+04 rev / 3.518E+17 -1.16 3.967E+04 / ch3och3 = ch3+ch3o 4.860E+55 -11.56 1.021E+05 rev / 1.173E+54 -11.88 2.310E+04 / ch3och3+oh = ch3och2+h2o 9.350E+05 2.29 -7.800E+02 rev / 1.030E+06 1.99 2.329E+04 / ch3och3+h = ch3och2+h2 7.721E+06 2.09 3.384E+03 rev / 1.964E+06 1.79 1.230E+04 / ch3och3+o = ch3och2+oh 1.855E-03 5.29 -1.090E+02 rev / 2.073E-04 5.00 6.708E+03 / ch3och3+ho2 = ch3och2+h2o2 1.680E+13 0.00 1.769E+04 rev / 1.098E+14 -0.62 1.029E+04 / ch3och3+ch3o2 = ch3och2+ch3o2h 1.680E+13 0.00 1.769E+04 rev / 2.287E+14 -0.80 7.270E+03 / ch3och3+ch3 = ch3och2+ch4 1.445E-06 5.73 5.699E+03 rev / 9.603E-06 5.43 1.509E+04 / ch3och3+o2 = ch3och2+ho2 4.100E+13 0.00 4.491E+04 rev / 1.895E+11 0.03 -3.659E+03 / ch3och3+ch3o = ch3och2+ch3oh 6.020E+11 0.00 4.074E+03 rev / 7.383E+10 -0.27 1.026E+04 / ch3och2 = ch2o+ch3 1.600E+13 0.00 2.550E+04 rev / 2.002E+12 0.00 2.400E+04 / ch3och2+ch3o = ch3och3+ch2o 2.410E+13 0.00 0.000E+00 rev / 1.250E+14 0.32 7.854E+04 / ch3och2+ch2o = ch3och3+hco 5.490E+03 2.80 5.862E+03 rev / 1.723E+03 3.10 1.162E+04 / ch3och2+ch3cho = ch3och3+ch3co 1.260E+12 0.00 8.499E+03 rev / 7.746E+11 0.28 1.698E+04 / ch3och2+ho2 = ch3och2o+oh 9.000E+12 0.00 0.000E+00 rev / 2.535E+15 -0.48 3.051E+04 / ch3och2o2 = ch3och2+o2 4.439E+19 -1.59 3.624E+04 rev / 2.000E+12 0.00 0.000E+00 / ch3och3+ch3och2o2 = ch3och2+ch3och2o2h 5.000E+12 0.00 1.769E+04 rev / 6.428E+13 -0.79 7.258E+03 / ch3och2o2+ch2o = ch3och2o2h+hco 1.000E+12 0.00 1.167E+04 rev / 4.035E+12 -0.50 6.997E+03 / ch3och2o2+ch3cho = ch3och2o2h+ch3co 2.800E+12 0.00 1.360E+04 rev / 1.000E+12 0.00 1.000E+04 / ch3och2o2h = ch3och2o+oh 4.384E+21 -1.94 4.387E+04 rev / 2.000E+13 0.00 0.000E+00 / ch3och2o = ch3o+ch2o 5.180E+12 -0.13 1.937E+04 rev / 1.000E+11 0.00 1.190E+04 / ch3och2o2 = ch2och2o2h 6.000E+10 0.00 2.158E+04 rev / 1.248E+12 -0.77 1.122E+04 / ch2och2o2h = oh+ch2o+ch2o 1.500E+13 0.00 2.076E+04 rev / 0.000E+00 0.00 0.000E+00 / o2ch2och2o2h = ch2och2o2h+o2 1.924E+19 -1.62 3.627E+04 rev / 7.000E+11 0.00 0.000E+00 / o2ch2och2o2h = ho2ch2ocho+oh 4.000E+10 0.00 1.858E+04 rev / 7.814E+03 1.49 5.881E+04 / ho2ch2ocho = och2ocho+oh 2.000E+16 0.00 4.050E+04 rev / 1.761E+09 1.49 -3.185E+03 / och2ocho = ch2o+hco2 5.964E+16 -1.50 1.962E+04 rev / 1.250E+11 0.00 1.190E+04 / c2h5o2 = c2h4+ho2 3.370E+55 -13.42 4.467E+04 rev / 1.290E+50 -12.28 2.130E+04 / c2h4o2h = c2h5+o2 2.150E+37 -8.21 2.802E+04 rev / 2.420E+35 -8.03 8.312E+03 / ch3o+ch3 = ch2o+ch4 2.400E+13 0.00 0.000E+00 rev / 8.270E+14 0.02 8.693E+04 / ch3och3+hco3 = ch3och2+hco3h 4.425E+04 2.60 1.391E+04 rev / 1.651E-05 4.61 1.172E+03 / och2ocho = hoch2oco 1.000E+11 0.00 1.400E+04 rev / 2.746E+08 -0.79 2.008E+04 / hoch2oco = hoch2o+co 2.177E+16 -2.69 1.720E+04 rev / 1.500E+11 0.00 4.800E+03 / hoch2oco = ch2oh+co2 8.672E+17 -3.45 1.908E+04 rev / 1.500E+11 0.00 3.520E+04 / ch2oh+ho2 = hoch2o+oh 1.000E+13 0.00 0.000E+00 rev / 8.515E+16 -1.09 3.309E+04 / hoch2o = ch2o+oh 1.482E+17 -1.21 2.124E+04 rev / 4.500E+15 -1.10 0.000E+00 / hoch2o = hco2h+h 1.000E+14 0.00 1.490E+04 rev / 5.904E+11 0.64 9.214E+03 / hco2h+m = co+h2o+m 2.300E+13 0.00 5.000E+04 rev / 1.422E+10 0.46 4.684E+04 / hco2h+m = co2+h2+m 1.500E+16 0.00 5.700E+04 rev / 2.399E+14 0.46 6.102E+04 / ch3och2o2+ch3och2o2 = ch3ocho+ch3och2oh+o2 6.630E+22 -4.50 0.000E+00 rev / 0.000E+00 0.00 0.000E+00 / ch3och2o2+ch3och2o2 = o2+ch3och2o+ch3och2o 1.547E+23 -4.50 0.000E+00 rev / 0.000E+00 0.00 0.000E+00 / ch3och2o = ch3ocho+h 1.745E+16 -0.66 1.172E+04 rev / 1.000E+13 0.00 7.838E+03 / ch3ocho = ch3+hco2 1.392E+18 -0.99 7.914E+04 rev / 1.000E+13 0.00 0.000E+00 / ch3ocho+o2 = ch3oco+ho2 1.000E+13 0.00 4.970E+04 rev / 8.437E+09 -0.96 8.000E+00 / ch3ocho+oh = ch3oco+h2o 2.340E+07 1.61 -3.500E+01 rev / 4.706E+06 0.32 2.291E+04 / ch3ocho+ho2 = ch3oco+h2o2 1.220E+12 0.00 1.700E+04 rev / 1.456E+12 -1.61 8.482E+03 / ch3ocho+o = ch3oco+oh 2.350E+05 2.50 2.230E+03 rev / 4.794E+03 1.21 7.925E+03 / ch3ocho+h = ch3oco+h2 4.550E+06 2.00 5.000E+03 rev / 2.113E+05 0.71 1.279E+04 / ch3ocho+ch3 = ch3oco+ch4 7.550E-01 3.46 5.481E+03 rev / 9.161E-01 2.17 1.375E+04 / ch3ocho+ch3o = ch3oco+ch3oh 5.480E+11 0.00 5.000E+03 rev / 1.227E+10 -1.26 1.106E+04 / ch3ocho+ch3o2 = ch3oco+ch3o2h 1.220E+12 0.00 1.700E+04 rev / 3.033E+12 -1.79 5.462E+03 / ch3oco = ch3o+co 7.451E+12 -1.76 1.715E+04 rev / 1.500E+11 0.00 3.000E+03 / ch3oco = ch3+co2 1.514E+12 -1.78 1.382E+04 rev / 1.500E+11 0.00 3.673E+04 / och2o2h = ch2o+ho2 1.278E+18 -1.80 1.046E+04 rev / 1.500E+11 0.00 1.190E+04 / och2o2h = hoch2o2 3.000E+11 0.00 8.600E+03 rev / 4.241E+08 0.95 2.620E+04 / hoch2o2+ho2 = hoch2o2h+o2 3.500E+10 0.00 -3.275E+03 rev / 1.046E+14 -0.84 3.487E+04 / ch3och3+hco2 = ch3och2+hco2h 1.000E+13 0.00 1.769E+04 rev / 4.884E+12 -0.26 2.508E+04 / hco2h = hco+oh 4.593E+18 -0.46 1.083E+05 rev / 1.000E+14 0.00 0.000E+00 / ch2o+hco2 = hco+hco2h 5.600E+12 0.00 1.360E+04 rev / 8.584E+11 0.04 2.675E+04 / hco2+ho2 = hco2h+o2 3.500E+10 0.00 -3.275E+03 rev / 3.699E+12 -0.29 5.269E+04 / hco2+h2o2 = hco2h+ho2 2.400E+12 0.00 1.000E+04 rev / 1.793E+11 0.36 2.479E+04 / hco2h+oh = h2o+co2+h 2.620E+06 2.06 9.160E+02 rev / 0.000E+00 0.00 0.000E+00 / hco2h+oh = h2o+co+oh 1.850E+07 1.51 -9.620E+02 rev / 0.000E+00 0.00 0.000E+00 / hco2h+h = h2+co2+h 4.240E+06 2.10 4.868E+03 rev / 0.000E+00 0.00 0.000E+00 / hco2h+h = h2+co+oh 6.030E+13 -0.35 2.988E+03 rev / 0.000E+00 0.00 0.000E+00 / hco2h+ch3 = ch4+co+oh 3.900E-07 5.80 2.200E+03 rev / 0.000E+00 0.00 0.000E+00 / hco2h+ho2 = h2o2+co+oh 1.000E+12 0.00 1.192E+04 rev / 0.000E+00 0.00 0.000E+00 / hco2h+o = co+oh+oh 1.770E+18 -1.90 2.975E+03 rev / 0.000E+00 0.00 0.000E+00 / ch2(s)+m = ch2+m 1.000E+13 0.00 0.000E+00 rev / 7.161E+15 -0.89 1.143E+04 / ch2(s)+ch4 = ch3+ch3 4.000E+13 0.00 0.000E+00 rev / 5.429E+15 -0.89 1.565E+04 / ch2(s)+c2h6 = ch3+c2h5 1.200E+14 0.00 0.000E+00 rev / 1.041E+14 -0.33 1.982E+04 / ch2(s)+o2 = co+oh+h 7.000E+13 0.00 0.000E+00 rev / 0.000E+00 0.00 0.000E+00 / ch2(s)+h2 = ch3+h 7.000E+13 0.00 0.000E+00 rev / 2.482E+17 -0.89 1.613E+04 / ch2(s)+h = ch+h2 3.000E+13 0.00 0.000E+00 rev / 1.509E+16 -0.89 1.442E+04 / ch2(s)+o = co+h+h 3.000E+13 0.00 0.000E+00 rev / 0.000E+00 0.00 0.000E+00 / ch2(s)+oh = ch2o+h 3.000E+13 0.00 0.000E+00 rev / 3.194E+18 -0.89 8.786E+04 / ch2(s)+co2 = ch2o+co 3.000E+12 0.00 0.000E+00 rev / 2.852E+15 -0.89 6.552E+04 / ch2(s)+ch3 = c2h4+h 2.000E+13 0.00 0.000E+00 rev / 2.671E+15 -0.06 6.884E+04 / ch2(s)+ch2co = c2h4+co 1.600E+14 0.00 0.000E+00 rev / 4.596E+15 -0.06 1.056E+05 / c2h3+o2 = ch2cho+o 3.500E+14 -0.61 5.260E+03 rev / 2.589E+12 0.12 6.459E+03 / end