! Marinov, N. M., Pitz, W.J., Westbrook, C.K., Hori, M., and Matsunaga, N. ! "An Experimental and Kinetic Calculation of the Promotion Effect of Hydrocarbons ! on the NO-NO2 Conversion in a Flow Reactor", ! Proceedings of the Combustion Institute, Volume 27, pp. 389-396, 1998. (UCRL-JC-129372). ! UCRL-WEB-204236 ! Review and release date: May 19, 2004. ! elements h o c n ar end species h2 h ch4 ch3 ch2 ch ch2o hco co2 co o2 o oh ho2 h2o2 h2o c2h hcco c2h2 c2h3 c2h4 c2h5 c2h6 ch2oh ch3o hccoh h2ccch c3h2 ch2(s) ch2co c2o hcoh ch3oh ch2hco c3h6 ac3h5 pc3h5 sc3h5 ch2chcho pc3h4 ac3h4 ch3co ch2chco ch3chco ch3hco chocho ic3h7 nc3h7 c2h5oh c2h4oh ch3choh ch2chch2o ch3ch2o hcooh c3h8 c2h5o2 c2h2oh c ar n nh nh2 nh3 nnh no no2 n2o hno cn hcn h2cn hcnn hcno hocn hnco nco n2 hno2 hono no3 hono2 c2coo c2cq c2jcq ccyc2o ccqcoo cc*ocq cjccq c*ccq cqcjcq cqcc*o cooccq cccoo ccqc*o ccjcq cjcqcq ccoocq cyccco ch3ooh ch3o2 c2h5ooh cccq cccoj cccho cqc*o ch2ch2ooh ac3h5o2 ac3h5o2h c6h10 c6h9 c2coj acetone hoc3h6 hoc3h6o2 hoc2h4o2 hooc2h4o2 hoc3h4o hoc3h4o3 hoccqcho hoccqc chchcho ch3no ch3ono ch3ono2 ch3no2 c3h5no2 end thermo end reactions oh+h2=h+h2o 2.14E+08 1.52 3449.0 !Marinov 1995a o+oh=o2+h 2.02E+14 -0.4 0.0 !Marinov 1995a o+h2=oh+h 5.06E+04 2.67 6290.0 !Marinov 1995a h+o2(+m)=ho2(+m) 4.52E+13 0.0 0.0 !Marinov 1995a low / 1.05E+19 -1.257 0.0 / !Marinov 1995a h2o/0.0/ h2/0.0/ n2/0.0/ ch4/10.0/ co2/3.8/ co/1.9/ h+o2(+n2)=ho2(+n2) 4.52E+13 0.0 0.0 !Marinov 1995a low / 2.03E+20 -1.59 0.0 / !Marinov 1995a h+o2(+h2)=ho2(+h2) 4.52E+13 0.0 0.0 !Marinov 1995a low / 1.52E+19 -1.133 0.0 / !Marinov 1995a h+o2(+h2o)=ho2(+h2o) 4.52E+13 0.0 0.0 !Marinov 1995a low / 2.10E+23 -2.437 0.0 / !Marinov 1995a oh+ho2=h2o+o2 2.13E+28 -4.827 3500.0 !Hippler 1995 dup oh+ho2=h2o+o2 9.10E+14 0.0 10964.0 !Hippler 1995 dup h+ho2=oh+oh 1.50E+14 0.0 1000.0 !Marinov 1995a h+ho2=h2+o2 6.63E+13 0.0 2126.0 !Tsang 1986x h+ho2=o+h2o 3.01E+13 0.0 1721.0 !Marinov 1995a o+ho2=o2+oh 3.25E+13 0.0 0.0 !Marinov 1995a oh+oh=o+h2o 3.57E+04 2.4 -2112.0 !Marinov 1995a h+h+m=h2+m 1.00E+18 -1.0 0.0 !Marinov 1995a h2o/0.0/ h2/0.0/ h+h+h2=h2+h2 9.20E+16 -0.6 0.0 !Marinov 1995a h+h+h2o=h2+h2o 6.00E+19 -1.25 0.0 !Marinov 1995a h+oh+m=h2o+m 2.21E+22 -2.0 0.0 !Marinov 1995a h2o/6.4/ h+o+m=oh+m 4.71E+18 -1.0 0.0 !Marinov 1995a h2o/6.4/ o+o+m=o2+m 1.89E+13 0.0 -1788.0 !Marinov 1995a ho2+ho2=h2o2+o2 4.20E+14 0.0 11982.0 !Marinov 1995a dup ho2+ho2=h2o2+o2 1.30E+11 0.0 -1629.0 !Marinov 1995a dup oh+oh(+m)=h2o2(+m) 1.24E+14 -0.37 0.0 !Marinov 1995a low / 3.04E+30 -4.63 2049.0 / !Marinov 1995a troe / 0.470 100.0 2000.0 1.0E+15/ h2o2+h=ho2+h2 1.98E+06 2.0 2435.0 !Marinov 1995a h2o2+h=oh+h2o 3.07E+13 0.0 4217.0 !Marinov 1995a h2o2+o=oh+ho2 9.55E+06 2.0 3970.0 !Marinov 1995a h2o2+oh=h2o+ho2 2.40E+00 4.042 -2162.0 !Marinov 1995a ch3+ch3(+m)=c2h6(+m) 9.22E+16 -1.174 636.0 !Walter 1990 low / 1.14E+36 -5.246 1705.0/ !Walter 1990 troe/ 0.405 1120.0 69.6 1.0E+15/ h2o/5.0/ h2/2.0/ co2/3.0/ co/2.0/ ch3+h(+m)=ch4(+m) 2.14E+15 -0.4 0.0 !Tsang 1986 low/ 3.31E+30 -4.0 2108.0 / !Marinov 1996 troe / 0.0 1.0E-15 1.0E-15 40.0/ h2o/5.0/ h2/2.0/ co2/3.0/ co/2.0/ ch4+h=ch3+h2 2.20E+04 3.0 8750.0 !Miller 1992 ch4+oh=ch3+h2o 4.19E+06 2.0 2547.0 !Marinov 1995 ch4+o=ch3+oh 6.92E+08 1.56 8485.0 !Marinov 1995 ch4+ho2=ch3+h2o2 1.12E+13 0.0 24640.0 !Marinov 1995 ch3+ho2=ch3o+oh 7.00E+12 0.0 0.0 !Troe 1993 ch3+ho2=ch4+o2 3.00E+12 0.0 0.0 !Marinov 1995 ch3+o=ch2o+h 8.00E+13 0.0 0.0 !Marinov 1995 ch3+o2=ch3o+o 1.45E+13 0.0 29209.0 !Klatt 1991 ch3+o2=ch2o+oh 3.51E+11 0.0 14640.0 !Marinov 1995 ch3+o2=ch3o2 9.03E+58 -15.0 17023.0 !Tsang 1986 ch3o2+o=ch3o+o2 2.60E+13 0.0 0.0 !Zellner 1988 ch3o2+h=ch3o+oh 9.64E+13 0.0 0.0 !Tsang 1986 ch3o2+ch3=ch3o+ch3o 2.40E+13 0.0 0.0 !Tsang 1986 ch3o2+ho2=ch3ooh+o2 2.29E+11 0.0 -1550.0 !Atkinson 1992 ch3ooh=ch3o+oh 6.00E+14 0.0 42300.0 !Lightfoot 1991 ch3ooh+oh=ch3o2+h2o 3.12E+6 2.0 -298.0 !This Study ch3o+h=ch3+oh 1.00E+13 0.0 0.0 !Marinov 1998 ch2oh+h=ch3+oh 1.00E+13 0.0 0.0 !Marinov 1998 ch3+oh=ch2(s)+h2o 2.65E+13 0.0 2186.0 !Humpfer 1994 ch3+oh=ch2+h2o 3.00E+06 2.0 2500.0 !Marinov 1996 ch3+oh=hcoh+h2 5.48E+13 0.0 2981.0 !Humpfer 1994 ch3+h=ch2+h2 9.00E+13 0.0 15100.0 !Miller 1992 ch3+m=ch+h2+m 6.90E+14 0.0 82469.0 !Markus 1992 ch3+m=ch2+h+m 1.90E+16 0.0 91411.0 !Markus 1992 ch3+oh(+m)=ch3oh(+m) 8.70E+13 0.1 0.0 !Fagerstrom 1993 low/ 8.84E+41 -7.4 626.0 / !Marinov 1996 troe / 0.025 1.0E-15 8000.0 3000.0/ h2o /10.0/ h2/2.0/ co2/3.0/ co/2.0/ ch3oh(+m)=ch2(s)+h2o 2.837e10 1.0 89871. !Marinov 1998 low / 1.78e49 -8.81 99369./ troe /0.9 740. 980. 5100./ h2o/10.0/ h2/2.0/ co2/3.0/ co/2.0/ ch3oh(+m)=hcoh+h2(+m) 4.2e9 1.12 85604. !Marinov 1998 low / 5.02e47 -8.402 94823./ troe/ 0.9 615. 915. 4615./ h2o /10.0/ h2/2.0/ co2/3.0/ co/2.0/ ch3oh(+m)=ch2o+h2(+m) 2.03e9 1.0 91443. !Marinov 1998 low /9.784e47 -8.4 101761./ troe/ 0.9 825. 1125. 5700./ h2o/10./ h2/2.0/ co2/3.0/ co/2.0/ ch3oh+oh=ch2oh+h2o 2.61E+05 2.182 -1344.0 !Tsang 1987 ch3oh+oh=ch3o+h2o 2.62E+06 2.056 916.0 !Tsang 1987 ch3oh+o=ch2oh+oh 3.88E+05 2.5 3080.0 !Tsang 1987 ch3oh+h=ch2oh+h2 1.70E+07 2.1 4868.0 !Tsang 1987 ch3oh+h=ch3o+h2 4.24E+06 2.1 4868.0 !Tsang 1987 ch3oh+ho2=ch2oh+h2o2 9.64E+10 0.0 12578.0 !Tsang 1987 ch2o+h(+m)=ch3o(+m) 5.40E+11 0.454 2600.0 !GRI-Mech2.11 low/ 1.50E+30 -4.80 5560./ troe/ 0.758 94. 1555. 4200./ h2o/5.0/ ch2o+h(+m)=ch2oh(+m) 5.40E+11 0.454 3600.0 !GRI-Mech2.11 low / 9.10E+31 -4.82 6530./ troe/ 0.7187 103. 1291. 4160./ h2o/5.0/ ch3o+ch3=ch2o+ch4 1.20E+13 0.0 0.0 !Tsang 1986 ch3o+h=ch2o+h2 2.00E+13 0.0 0.0 !Miller 1992 ch2oh+h=ch2o+h2 2.00E+13 0.0 0.0 !Miller 1992 ch3o+oh=ch2o+h2o 1.00E+13 0.0 0.0 !Miller 1992 ch2oh+oh=ch2o+h2o 1.00E+13 0.0 0.0 !Miller 1992 ch3o+o=ch2o+oh 1.00E+13 0.0 0.0 !Miller 1992 ch2oh+o=ch2o+oh 1.00E+13 0.0 0.0 !Miller 1992 ch3o+o2=ch2o+ho2 6.30E+10 0.0 2600.0 !Miller 1992 ch3o+co=ch3+co2 4.68E+02 3.16 5380.0 !Wantuck 1987 ch2oh+o2=ch2o+ho2 1.57E+15 -1.0 0.0 !Baulch 1992 dup ch2oh+o2=ch2o+ho2 7.23E+13 0.0 3577.0 !Baulch 1992 dup hcoh+oh=hco+h2o 2.00E+13 0.0 0.0 !Marinov 1996 hcoh+h=ch2o+h 2.00E+14 0.0 0.0 !Marinov 1996 hcoh+o=co2+h+h 5.00E+13 0.0 0.0 !Marinov 1996 hcoh+o=co+oh+h 3.00E+13 0.0 0.0 !Marinov 1996 hcoh+o2=co+oh+oh 1.00E+13 0.0 0.0 !Marinov 1998 hcoh+o2=co2+h2o 1.00E+13 0.0 0.0 !Marinov 1998 hcoh=ch2o 2.10E+19 -3.07 31700.0 !Marinov 1998 ch2+h=ch+h2 1.00E+18 -1.56 0.0 !Miller 1992 ch2+oh=ch+h2o 1.13E+07 2.0 3000.0 !Miller 1992 ch2+oh=ch2o+h 2.50E+13 0.0 0.0 !Miller 1992 ch2+co2=ch2o+co 1.10E+11 0.0 1000.0 !Miller 1992 ch2+o=co+h+h 5.00E+13 0.0 0.0 !Miller 1992 ch2+o=co+h2 3.00E+13 0.0 0.0 !Miller 1992 ch2+o2=ch2o+o 3.29E+21 -3.3 2868.0 !Marinov 1996 ch2+o2=co2+h+h 3.29E+21 -3.3 2868.0 !Marinov 1996 ch2+o2=co2+h2 1.01E+21 -3.3 1508.0 !Marinov 1996 ch2+o2=co+h2o 7.28E+19 -2.54 1809.0 !Marinov 1996 ch2+o2=hco+oh 1.29E+20 -3.3 284.0 !Marinov 1996 ch2+ch3=c2h4+h 4.00E+13 0.0 0.0 ! Miller 1992 ch2+ch2=c2h2+h+h 4.00E+13 0.0 0.0 ! Miller 1992 ch2+hcco=c2h3+co 3.00E+13 0.0 0.0 ! Miller 1992 ch2+c2h2=h2ccch+h 1.20E+13 0.0 6600.0 ! Miller 1992 ch2(s)+m=ch2+m 1.00E+13 0.0 0.0 ! Miller 1992 h /12.0/ c2h2 /4.0/ h2o/3.0/ ch2(s)+ch4=ch3+ch3 4.00E+13 0.0 0.0 ! Miller 1992 ch2(s)+c2h6=ch3+c2h5 1.20E+14 0.0 0.0 ! Miller 1992 ch2(s)+o2=co+oh+h 7.00E+13 0.0 0.0 ! Miller 1992 ch2(s)+h2=ch3+h 7.00E+13 0.0 0.0 ! Miller 1992 ch2(s)+c2h2=h2ccch+h 1.50E+14 0.0 0.0 ! Canosa-Mas85 ch2(s)+c2h4=ac3h5+h 1.30E+14 0.0 0.0 ! Canosa-Mas85 ch2(s)+o=co+h+h 3.00E+13 0.0 0.0 ! Miller 1992 ch2(s)+oh=ch2o+h 3.00E+13 0.0 0.0 ! Miller 1992 ch2(s)+h=ch+h2 3.00E+13 0.0 0.0 ! Miller 1992 ch2(s)+co2=ch2o+co 3.00E+12 0.0 0.0 ! Miller 1992 ch2(s)+ch3=c2h4+h 2.00E+13 0.0 0.0 ! Miller 1992 ch2(s)+ch2co=c2h4+co 1.60E+14 0.0 0.0 ! Miller 1992 ch+o2=hco+o 3.30E+13 0.0 0.0 ! Miller 1992 ch+o=co+h 5.70E+13 0.0 0.0 ! Miller 1992 ch+oh=hco+h 3.00E+13 0.0 0.0 ! Miller 1992 ch+co2=hco+co 3.40E+12 0.0 690.0 ! Miller 1992 ch+h2o=ch2o+h 1.17E+15 -0.75 0.0 ! Miller 1992 ch+ch2o=ch2co+h 9.46E+13 0.0 -515.0 ! Miller 1992 ch+c2h2=c3h2+h 1.00E+14 0.0 0.0 ! Miller 1992 ch+ch2=c2h2+h 4.00E+13 0.0 0.0 ! Miller 1992 ch+ch3=c2h3+h 3.00E+13 0.0 0.0 ! Miller 1992 ch+ch4=c2h4+h 6.00E+13 0.0 0.0 ! Miller 1992 ch2o+oh=hco+h2o 3.43E+09 1.18 -447.0 ! Tsang 1986 ch2o+h=hco+h2 2.19E+08 1.77 3000.0 ! Miller 1992 ch2o+m=hco+h+m 3.31E+16 0.0 81000.0 ! Miller 1992 ch2o+o=hco+oh 1.80E+13 0.0 3080.0 ! Miller 1992 hco+o2=ho2+co 7.58E+12 0.0 410.0 ! Timonen 1988 hco+m=h+co+m 1.86E+17 -1.0 17000.0 ! Timonen 1987 h2o/5.0/ h2/1.87/ co2/3.0/ co/1.87/ ch4/2.81/ hco+oh=h2o+co 1.00E+14 0.0 0.0 ! Miller 1992 hco+h=co+h2 1.19E+13 0.25 0.0 ! Miller 1992 hco+o=co+oh 3.00E+13 0.0 0.0 ! Miller 1992 hco+o=co2+h 3.00E+13 0.0 0.0 ! Miller 1992 co+oh=co2+h 9.42E+03 2.25 -2351.0 !Marinov 1996 co+o+m=co2+m 6.17E+14 0.0 3000.0 ! Miller 1992 co+o2=co2+o 2.53E+12 0.0 47688.0 ! Miller 1992 co+ho2=co2+oh 5.80E+13 0.0 22934.0 ! Miller 1992 c2h6+ch3=c2h5+ch4 5.50E-01 4.0 8300.0 ! Miller 1992 c2h6+h=c2h5+h2 5.40E+02 3.5 5210.0 ! Miller 1992 c2h6+o=c2h5+oh 3.00E+07 2.0 5115.0 ! Miller 1992 c2h6+oh=c2h5+h2o 7.23E+06 2.0 864.0 ! Baulch 1992 c2h5+h=c2h4+h2 1.25E+14 0.0 8000.0 ! Marinov 1995 c2h5+h=ch3+ch3 3.00E+13 0.0 0.0 ! Warnatz 1984 c2h5+h=c2h6 3.00E+13 0.0 0.0 ! Marinov 1998 c2h5+oh=c2h4+h2o 4.00E+13 0.0 0.0 ! Marinov 1995 c2h5+o=ch3+ch2o 1.00E+14 0.0 0.0 ! Herron 1988 c2h5+ho2=c2h6+o2 3.00E+12 0.0 0.0 ! Marinov 1998 c2h5+ho2=ch3ch2o+oh 3.00E+13 0.0 0.0 ! Tsang 1986 c2h5+o2=c2h4+ho2 2.89E+28 -5.4 7585.0 ! This Study c2h5+o2=c2h5o2 2.22E+52 -13.25 9756.0 ! This Study c2h5+o2=ch3hco+oh 4.90E+11 -0.48 8357.0 ! This Study c2h5+o2=ch2ch2ooh 5.18E+42 -10.72 8576.0 ! This Study c2h5o2=ch2ch2ooh 2.96E+55 -14.24 37892.0 ! This Study c2h5o2=c2h4+ho2 7.37E+54 -13.55 41070.0 ! This Study c2h5o2+ho2=c2h5ooh+o2 2.29E+11 0.0 -1550.0 ! This Study c2h5ooh=ch3ch2o+oh 6.00E+14 0.0 42300.0 ! This Study ch2ch2ooh=c2h4+ho2 6.87E+45 -11.09 23227.0 ! This Study ch2ch2ooh+o2=hooc2h4o2 1.00E+12 0.0 -1100.0 ! This Study hooc2h4o2=cqc*o+oh 6.00E+10 0.0 24500.0 ! This Study cqc*o=ch2o+hco+oh 6.00E+14 0.0 42300.0 ! This Study c2h4+oh=c2h4oh 1.29E+12 0.0 -817.0 ! Atkinson 1986 c2h4oh+o2=hoc2h4o2 1.00E+12 0.0 -1100.0 ! This Study hoc2h4o2=ch2o+ch2o+oh 6.00E+10 0.0 24500.0 ! This Study c2h4+oh=c2h3+h2o 2.02E+13 0.0 5936.0 ! Miller 1992 c2h4+o=ch3+hco 1.02E+07 1.88 179.0 ! Baulch 1994 c2h4+o=ch2hco+h 3.39E+06 1.88 179.0 ! Baulch 1994 c2h4+ch3=c2h3+ch4 6.62E+00 3.7 9500.0 ! Marinov 1995 c2h4+h=c2h3+h2 3.36E-07 6.0 1692.0 ! Dagaut 1990 c2h4+h(+m)=c2h5(+m) 1.08E+12 0.454 1822.0 ! Feng 1993 low / 1.112E+34 -5.0 4448.0 / ! Marinov 1996 troe / 1.0 1.0E-15 95.0 200.0 / h2o /5.0/ h2/2.0/ co2/3.0/ co/2.0/ c2h4(+m)=c2h2+h2(+m) 1.80E+13 0.0 76000. ! Marinov 1997 low / 1.50E+15 0.0 55443. / c2h3+h(+m)=c2h4(+m) 6.10E+12 0.27 280. !GRI-Mech2.11 low/9.80E+29 -3.86 3320./ troe/ 0.782 208. 2663. 6095./ h2o/5.0/ c2h3+h=c2h2+h2 4.00E+13 0.0 0.0 ! Miller 1992 c2h3+o=ch2co+h 3.00E+13 0.0 0.0 ! Miller 1992 c2h3+o2=ch2o+hco 1.70E+29 -5.312 6500.0 ! Marinov 1997 c2h3+o2=ch2hco+o 5.50E+14 -0.611 5260.0 ! Marinov 1997 c2h3+o2=c2h2+ho2 2.12E-06 6.0 9484.0 !cfm/nmm 1996 c2h3+oh=c2h2+h2o 2.00E+13 0.0 0.0 ! Miller 1992 c2h3+c2h=c2h2+c2h2 3.00E+13 0.0 0.0 ! Miller 1992 c2h3+ch=ch2+c2h2 5.00E+13 0.0 0.0 ! Miller 1992 c2h3+ch3=ac3h5+h 4.73E+02 3.7 5677.0 ! Marinov 1996 c2h3+ch3=c3h6 4.46E+56 -13.0 13865.0 ! Marinov 1996 c2h3+ch3=c2h2+ch4 2.00E+13 0.0 0.0 ! Fahr 1991 c2h2+oh=c2h+h2o 3.37E+07 2.0 14000.0 ! Miller 1992 c2h2+oh=hccoh+h 5.04E+05 2.3 13500.0 ! Miller 1992 c2h2+oh=ch2co+h 2.18E-04 4.5 -1000.0 ! Miller 1992 c2h2+oh=c2h2oh 1.02E+12 0.0 463.0 ! This Study c2h2+oh=ch3+co 4.83E-04 4.0 -2000.0 ! Miller 1992 hccoh+h=ch2co+h 1.00E+13 0.0 0.0 ! Miller 1992 c2h2oh+o2=chocho+oh 2.00E+12 0.0 0.0 ! This Study c2h2oh+h=ch2hco+h 1.00E+14 0.0 0.0 ! This Study c2h2+o=ch2+co 6.12E+06 2.0 1900.0 ! Marinov 1996 c2h2+o=hcco+h 1.43E+07 2.0 1900.0 ! Marinov 1996 c2h2+o=c2h+oh 3.16E+15 -0.6 15000.0 ! Miller 1992 c2h2+ch3=c2h+ch4 1.81E+11 0.0 17289.0 ! Tsang 1986 c2h2+o2=hcco+oh 4.00e+07 1.5 30100.0 ! Marinov 1997 c2h2+m=c2h+h+m 4.20E+16 0.0 107000.0 ! Miller 1992 c2h2+h (+m)=c2h3(+m) 3.11E+11 0.58 2589.0 ! Knyazev 1995 low / 2.25E+40 -7.269 6577.0 / ! Marinov 1996 troe /1.0 1.0E-15 675.0 1.0E+15 / h2o /5.0/ h2/2.0/ co2/3.0/ co/2.0/ c2h5oh(+m)=ch3+ch2oh(+m) 5.71E+23 -1.68 94405.0 !Marinov 1998 low /3.11E+85 -18.84 113095./ troe/0.5 550. 825. 6100./ h2o/5./ h2/2.0/ co2/3.0/ co/2.0/ c2h5oh(+m)=c2h5+oh(+m) 2.40E+23 -1.62 99535.0 !Marinov 1998 low /5.11E+85 -18.80 118768./ troe/0.5 650. 800. 1.e15/ h2o/5./ h2/2.0/ co2/3.0/ co/2.0/ c2h5oh(+m)=c2h4+h2o(+m) 1.57E+13 0.14 65684.0 !Marinov 1998 low/6.68E+82 -18.7 85500./ troe/6.7 1.e-15 460. 1.e15/ h2o/5./ c2h5oh(+m)=ch3hco+h2(+m) 1.67E+9 1.0 90820.0 !Marinov 1998 low /2.04e82 -17.94 111674./ troe/0.9 900. 1120. 7500./ h2o/5./ c2h5oh+oh=c2h4oh+h2o 1.74E+11 0.27 600.0 !Marinov 1998 c2h5oh+oh=ch3choh+h2o 4.64E+11 0.15 0.0 !Marinov 1998 c2h5oh+oh=ch3ch2o+h2o 7.46E+11 0.30 1634.0 !Marinov 1998 c2h5oh+h=c2h4oh+h2 1.23E+7 1.8 5098.0 !Marinov 1998 c2h5oh+h=ch3choh+h2 2.58E+7 1.65 2827.0 !Marinov 1998 c2h5oh+h=ch3ch2o+h2 1.50E+7 1.60 3038.0 !Marinov 1998 c2h5oh+o=c2h4oh+oh 9.41E+7 1.70 5459.0 !Marinov 1998 c2h5oh+o=ch3choh+oh 1.88E+7 1.85 1824.0 !Marinov 1998 c2h5oh+o=ch3ch2o+oh 1.58E+7 2.00 4448.0 !Marinov 1998 c2h5oh+ch3=c2h4oh+ch4 1.33E+2 3.18 9362.0 !Marinov 1998 c2h5oh+ch3=ch3choh+ch4 4.44E+2 2.90 7690.0 !Marinov 1998 c2h5oh+ch3=ch3ch2o+ch4 1.34E+2 2.92 7452.0 !Marinov 1998 c2h5oh+ho2=ch3choh+h2o2 7.20E+3 2.55 10750.0 !Marinov 1998 c2h5oh+ho2=c2h4oh+h2o2 1.00E+4 2.55 15750.0 !Marinov 1998 c2h5oh+ho2=ch3ch2o+h2o2 2.50E+12 0.0 24000.0 !Marinov 1998 ch3ch2o+m=ch3hco+h+m 1.16E+35 -5.89 25274.0 !Marinov 1998 ch3ch2o+m=ch3+ch2o+m 1.35E+38 -6.96 23800.0 !Marinov 1998 ch3ch2o+o2=ch3hco+ho2 4.00E+10 0.0 1100.0 !Hartmann 1990 ch3ch2o+co=c2h5+co2 4.68E+2 3.16 5380.0 !Marinov 1998 ch3ch2o+h=ch3+ch2oh 1.00E+13 0.0 0.0 !Marinov 1998 ch3ch2o+h=ch3hco+h2 1.00E+13 0.0 0.0 !Marinov 1998 ch3ch2o+oh=ch3hco+h2o 1.00E+13 0.0 0.0 !Marinov 1998 ch3choh+o2=ch3hco+ho2 4.82E+14 0.0 5017.0 !Marinov 1998 dup ch3choh+o2=ch3hco+ho2 8.43E+15 -1.2 0.0 !Marinov 1998 dup ch3choh+ch3=ic3h7+oh 2.00E+13 0.0 0.0 !Marinov 1998 ch3choh+o=ch3hco+oh 1.00E+14 0.0 0.0 !Marinov 1998 ch3choh+h=ch3hco+h2 1.00E+13 0.0 0.0 !Marinov 1998 ch3choh+h=ch3+ch2oh 1.00E+13 0.0 0.0 !Marinov 1998 ch3choh+ho2=ch3hco+oh+oh 4.00E+13 0.0 0.0 !Marinov 1998 ch3choh+oh=ch3hco+h2o 5.00E+12 0.0 0.0 !Marinov 1998 ch3choh+m=ch3hco+h+m 1.00E+14 0.0 25000.0 !Marinov 1998 ch3hco+oh=ch3co+h2o 9.24E+6 1.5 -962.0 !Taylor 1996 ch3hco+oh=ch2hco+h2o 1.72E+5 2.4 815.0 !Taylor 1996 ch3hco+oh=ch3+hcooh 3.00E+15 -1.076 0.0 !Marinov 1998 ch3hco+o=ch3co+oh 1.77E+18 -1.9 2975.0 !Marinov 1998 ch3hco+o=ch2hco+oh 3.72E+13 -0.2 3556.0 !Marinov 1998 ch3hco+h=ch3co+h2 4.66E+13 -0.35 2988.0 !Marinov 1998 ch3hco+h=ch2hco+h2 1.85E+12 0.40 5359.0 !Marinov 1998 ch3hco+ch3=ch3co+ch4 3.90E-7 5.8 2200.0 !Marinov 1998 ch3hco+ch3=ch2hco+ch4 2.45E+1 3.15 5727.0 !Marinov 1998 ch3hco+ho2=ch3co+h2o2 2.40E+19 -2.2 14030.0 !Marinov 1998 ch3hco+ho2=ch2hco+h2o2 2.32E+11 0.40 14864.0 !Marinov 1998 hcooh+m=co+h2o+m 2.09E+14 0.0 40400.0 !Saito 1984 hcooh+m=co2+h2+m 1.35E+15 0.0 60600.0 !Saito 1984 hcooh+oh=co2+h2o+h 2.62E+6 2.056 916.0 !Marinov 1998 hcooh+oh=co+h2o+oh 1.85E+7 1.5 -962.0 !Marinov 1998 hcooh+h=co2+h2+h 4.24E+6 2.1 4868.0 !Marinov 1998 hcooh+h=co+h2+oh 6.06E+13 -0.35 2988.0 !Marinov 1998 hcooh+ch3=ch4+co+oh 3.90E-7 5.8 2200.0 !Marinov 1998 hcooh+ho2=co+h2o2+oh 2.40E+19 -2.2 14030.0 !Marinov 1998 hcooh+o=co+oh+oh 1.77E+18 -1.9 2975.0 !Marinov 1998 ch2hco+h=ch3+hco 5.00E+13 0.0 0.0 !Marinov 1998 ch2hco+h=ch2co+h2 2.00E+13 0.0 0.0 !Marinov 1998 ch2hco+o=ch2o+hco 1.00E+14 0.0 0.0 !Marinov 1996 ch2hco+oh=ch2co+h2o 3.00E+13 0.0 0.0 !Marinov 1996 ch2hco+o2=ch2o+co+oh 3.00E+10 0.0 0.0 !Baulch 1992 ch2hco+ch3=c2h5+co+h 4.90E+14 -0.50 0.0 !Marinov 1998 ch2hco+ho2=ch2o+hco+oh 7.00E+12 0.0 0.0 !Marinov 1998 ch2hco+ho2=ch3hco+o2 3.00E+12 0.0 0.0 !Marinov 1998 ch2hco=ch3+co 1.17E+43 -9.83 43756.0 !Marinov 1998 ch2hco=ch2co+h 1.81E+43 -9.61 45868.0 !Marinov 1998 chocho(+m)=ch2o+co(+m) 4.27E+12 0.0 50600.0 ! Marinov 1995 low / 8.91E+16 0.0 49200.0 / ! Marinov 1995 chocho=co+co+h2 4.07E+42 -8.5 69278.0 ! Marinov 1996 chocho+oh=hco+co+h2o 1.00E+13 0.0 0.0 ! Marinov 1995 chocho+o=hco+co+oh 7.24E+12 0.0 1970.0 ! Marinov 1995 chocho+h=ch2o+hco 1.00E+12 0.0 0.0 ! Marinov 1995 chocho+ho2=hco+co+h2o2 1.70E+12 0.0 10700.0 ! Marinov 1995 chocho+ch3=hco+co+ch4 1.74E+12 0.0 8440.0 ! Marinov 1995 chocho+o2=hco+co+ho2 1.00E+14 0.0 37000.0 ! Marinov 1995 ch3co(+m)=ch3+co(+m) 3.00E+12 0.0 16722.0 ! Warnatz 1984 low / 1.20E+15 0.0 12518.0 / ! Warnatz 1984 ch2co+o=co2+ch2 1.75E+12 0.0 1350.0 ! Marinov 1995 ch2co+h=ch3+co 2.71E+4 2.75 714.0 ! Marinov 1996 ch2co+h=hcco+h2 2.00E+14 0.0 8000.0 ! Marinov 1996 ch2co+o=hcco+oh 1.00E+13 0.0 8000.0 ! Miller 1992 ch2co+oh=hcco+h2o 1.00E+13 0.0 2000.0 ! Marinov 1996 ch2co+oh=ch2oh+co 3.73E+12 0.0 -1013.0 ! Brown 1989 ch2co(+m)=ch2+co(+m) 3.00E+14 0.0 70980.0 ! Miller 1992 low / 3.60E+15 0.0 59270.0 / ! Miller 1992 c2h+h2=c2h2+h 4.09E+05 2.39 864.3 ! Miller 1992 c2h+o=ch+co 5.00E+13 0.0 0.0 ! Miller 1992 c2h+oh=hcco+h 2.00E+13 0. 0.0 ! Miller 1992 c2h+o2=co+co+h 9.04E+12 0.0 -457.0 ! Opansky 1993 hcco+c2h2=h2ccch+co 1.00E+11 0.0 3000.0 ! Miller 1992 hcco+h=ch2(s)+co 1.00E+14 0.0 0.0 ! Miller 1992 hcco+o=h+co+co 8.00E+13 0.0 0.0 ! Peeters 1995 hcco+o=ch+co2 2.95E+13 0.0 1113.0 ! Peeters 1995 hcco+o2=hco+co+o 2.50E+8 1.0 0.0 ! Marinov 1997 hcco+o2=co2+hco 2.40E+11 0.0 -854.0 ! Marinov 1997 hcco+ch=c2h2+co 5.00E+13 0.0 0.0 ! Miller 1992 hcco+hcco=c2h2+co+co 1.00E+13 0.0 0.0 ! Miller 1992 hcco+oh=c2o+h2o 3.00E+13 0.0 0.0 ! Miller 1992 c2o+h=ch+co 1.00E+13 0.0 0.0 ! Miller 1992 c2o+o=co+co 5.00E+13 0.0 0.0 ! Miller 1992 c2o+oh=co+co+h 2.00E+13 0.0 0.0 ! Miller 1992 c2o+o2=co+co+o 2.00E+13 0.0 0.0 ! Miller 1992 c3h8(+m)=c2h5+ch3(+m) 7.90E+22 -1.8 88629.0 ! Tsang 1988 low / 7.237E+27 -2.88 67448.0 / ! Al-Alami 1983 troe /1.0 1.0E-15 1500.0 1.0E+15/ h2o/5.0/ co2/3.0/ co/2.0/ h2/2.0/ ic3h7+ho2=c3h8+o2 3.00E+12 0.0 0.0 !Marinov 1998 nc3h7+ho2=c3h8+o2 3.00E+12 0.0 0.0 !Marinov 1998 c3h8+ho2=nc3h7+h2o2 4.76E+04 2.55 16492.0 ! Tsang 1988 c3h8+ho2=ic3h7+h2o2 9.64E+03 2.6 13909.0 ! Tsang 1988 c3h8+oh=nc3h7+h2o 3.16E+07 1.8 934.0 ! Cohen 1991 c3h8+oh=ic3h7+h2o 7.08E+06 1.9 -159.0 ! Cohen 1991 c3h8+o=nc3h7+oh 3.73E+06 2.4 5504.0 ! Cohen 1986 c3h8+o=ic3h7+oh 5.48E+05 2.5 3139.0 ! Cohen 1986 c3h8+h=ic3h7+h2 1.30E+06 2.4 4471.0 ! Tsang 1988 c3h8+h=nc3h7+h2 1.33E+06 2.54 6756.0 ! Tsang 1988 c3h8+ch3=nc3h7+ch4 9.04E-01 3.65 7153.0 ! Tsang 1988 c3h8+ch3=ic3h7+ch4 1.51E+00 3.46 5480.0 ! Tsang 1988 c3h8+c2h3=ic3h7+c2h4 1.00E+03 3.1 8830.0 ! Tsang 1988 c3h8+c2h3=nc3h7+c2h4 6.00E+02 3.3 10500.0 ! Tsang 1988 c3h8+c2h5=ic3h7+c2h6 1.51E+00 3.46 7470.0 ! Tsang 1988 c3h8+c2h5=nc3h7+c2h6 9.03E-01 3.65 9140.0 ! Tsang 1988 c3h8+ac3h5=c3h6+nc3h7 2.35E+02 3.3 19842.0 ! Tsang 1988 c3h8+ac3h5=c3h6+ic3h7 7.83E+01 3.3 18169.0 ! Tsang 1988 nc3h7(+m)=c2h4+ch3(+m) 1.23E+13 -0.1 30202.0 ! Bencsura 1992 low / 5.485E+49 -10.0 35766.0 / ! Bencsura 1992 troe / 2.17 1.0E-15 251.0 1185.0 / h2o /5.0/ h2/2.0/ co2/3.0/ co/2.0/ c3h6+h(+m)=ic3h7(+m) 5.70E+09 1.16 874.0 ! Seakins 1993 low / 1.64E+54 -11.1 9364.0 / ! Marinov 1996 troe / 1.0 1.0E-15 260.0 3000.0 / h2o /5.0/ h2/2.0/ co2/3.0/ co/2.0/ ic3h7+o2=c2coo 1.75E+58 -14.89 12608.0 !This Study ic3h7+o2=c2jcq 7.06E+27 -5.91 4802.0 !This Study ic3h7+o2=c3h6+ho2 1.88E+20 -2.69 7109.0 !This Study ic3h7+o2=ccyc2o+oh 4.54E+4 1.55 5000.0 !This Study c2coo=c2jcq 6.18E+61 -16.03 43008.0 !This Study c2coo=c3h6+ho2 1.51E+72 -18.69 51699.0 !This Study c2coo=ccyc2o+oh 1.95E+57 -14.99 49595.0 !This Study c2coo+ho2=c2cq+o2 2.29E+11 0.0 -1550.0 !This Study c2cq=c2coj+oh 6.00E+14 0.0 42300.0 !This Study c2coj=acetone+h 2.00E+14 0.0 21500.0 !Batt 1979 c2coj=ch3+ch3hco 4.00E+14 0.0 17200.0 !Batt 1979 c2coj+o2=acetone+ho2 4.90E+10 0.0 1590.0 !Heicklen 1988 c2coj+co=ic3h7+co2 4.68E+2 3.16 5380.0 !This Study c2jcq=ch2hco+ch3+oh 8.19E+7 0.46 29230.0 !This Study c2jcq+o2=ccqcoo 1.08E+31 -6.04 5019.0 !This Study c2jcq+o2=cc*ocq+oh 1.15E+27 -4.61 10312.0 !This Study c2jcq+o2=cjcqcq 6.98E+30 -6.14 11470.0 !This Study c2jcq+o2=c*ccq+ho2 1.41E+42 -9.22 20724.0 !This Study ccqcoo=cc*ocq+oh 2.46E+23 -3.95 24702.0 !This Study ccqcoo=cjcqcq 4.72E+25 -4.89 26209.0 !This Study cjcqcq=cc*ocq+oh 1.17E+24 -4.71 21921.0 !This Study cjcqcq=c*ccq+ho2 3.53E+20 -2.8 18874.0 !This Study cc*ocq=ch3co+ch2o+oh 6.00E+14 0.0 42300.0 !This Study acetone+oh=ch2co+ch3+h2o 7.23E+6 2.0 864.0 !This Study acetone+o=ch2co+ch3+oh 3.00E+7 2.0 5115.0 !This Study acetone+h=ch2co+ch3+h2 5.40E+2 3.5 5210.0 !This Study nc3h7+o2=cccoo 8.57E+46 -10.79 11555.0 !This Study nc3h7+o2=cccho+oh 2.04E+16 -1.29 18186.0 !This Study nc3h7+o2=ccjcq 1.45E+36 -7.61 13874.0 !This Study nc3h7+o2=c3h6+ho2 3.83E+26 -4.44 7724.0 !This Study nc3h7+o2=cjccq 3.47E+45 -10.05 19704.0 !This Study cccoo=c3h6+ho2 1.88E+61 -14.94 49716.0 !This Study cccoo=cjccq 4.18E+34 -7.33 31801.0 !This Study cccoo=ccjcq 1.61E+42 -9.75 35783.0 !This Study ccjcq=c3h6+ho2 2.19E+30 -6.11 18849.0 !This Study ccjcq=ccyc2o+oh 1.01E+20 -3.36 20038.0 !This Study cjccq=c3h6+ho2 1.22E+57 -13.84 43391.0 !This Study cjccq=cyccco+oh 2.23E+14 -1.26 18153.0 !This Study ccjcq+o2=ccoocq 1.00E+36 -7.67 6314.0 !This Study ccjcq+o2=cjcqcq 5.00E+34 -7.22 13951.0 !This Study ccjcq+o2=c*ccq+ho2 8.54E+43 -9.53 22551.0 !This Study ccjcq+o2=ccqc*o+oh 6.13E+28 -5.05 11272.0 !This Study ccqc*o=ch3hco+hco+oh 6.00E+14 0.0 42300.0 !This Study cqcc*o=ch2hco+ch2o+oh 6.00E+14 0.0 42300.0 !This Study ccoocq=cjcqcq 3.21E+37 -8.25 34660.0 !This Study ccoocq=ccqc*o+oh 1.21E+30 -5.85 28978.0 !This Study cjcqcq=ccqc*o+oh 1.41E+33 -7.14 28454.0 !This Study c*ccq=ch2chch2o+oh 6.00E+14 0.0 42300.0 !This Study cjccq+o2=cooccq 6.92E+28 -5.32 4441.0 !This Study cjccq+o2=cqcc*o+oh 1.46E+29 -5.5 10127.0 !This Study cjccq+o2=cqcjcq 4.81E+32 -6.71 12303.0 !This Study cjccq+o2=c*ccq+ho2 1.76E+41 -8.76 20150.0 !This Study cooccq=cqcc*o+oh 1.81E+18 -2.68 20340.0 !This Study cooccq=cqcjcq 4.08E+30 -6.24 30612.0 !This Study cooccq=c*ccq+ho2 1.06E+38 -7.99 40074.0 !This Study cqcjcq=cqcc*o+oh 2.37E+30 -6.77 27650.0 !This Study cqcjcq=c*ccq+ho2 1.44E+24 -4.03 19130.0 !This Study cccoo+ho2=cccq+o2 2.29E+11 0.00 -1550.0 !This Study cccq=cccoj+oh 6.00E+14 0.0 42300.0 !This Study cccoj+o2=cccho+ho2 1.95E+11 0.0 1980.0 !This Study cccoj+co=nc3h7+co2 4.68E+2 3.16 5380.0 !This Study cccoj+m=c2h5+ch2o+m 1.35E+38 -6.96 23800.0 !This Study cccoj+m=cccho+h+m 1.16E+35 -5.89 25274.0 !This Study cccho+oh=c2h5+co+h2o 1.00E+10 1.0 0.0 !This Study cccho+o=c2h5+co+oh 7.24E+12 0.0 1970.0 !This Study cccho+h=c2h5+co+h2 3.98E+13 0.0 4200.0 !This Study ic3h7+h=c2h5+ch3 5.00E+13 0.0 0.0 ! Tsang 1988 nc3h7+h=c2h5+ch3 1.00E+14 0.0 0.0 ! Tsang 1988 c3h6=c2h2+ch4 2.50E+12 0.0 70000.0 ! Hidaka 1992 c3h6=ac3h4+h2 3.00E+13 0.0 80000.0 ! Hidaka 1992 pc3h5+h=c3h6 1.00E+14 0.0 0.0 !Marinov 1998 sc3h5+h=c3h6 1.00E+14 0.0 0.0 !Marinov 1998 c3h6+ho2=ac3h5+h2o2 9.64E+03 2.6 13910.0 ! Tsang 1991 c3h6+oh=hoc3h6 2.92E+12 0.0 -1000.0 ! Atkinson 1986 hoc3h6+o2=hoc3h6o2 1.00E+12 0.0 -1100.0 !This Study hoc3h6o2=ch3hco+ch2o+oh 6.00E+10 0.0 26000.0 !This Study hoc3h6o2+ho2=hoccqc+o2 2.29E+11 0.0 -1550.0 !This Study hoccqc=ch2oh+ch3hco+oh 6.00E+14 0.0 42300.0 !This Study c3h6+oh=ac3h5+h2o 2.60E+06 2.0 -298.0 !Tsang 1991 c3h6+oh=sc3h5+h2o 1.11E+06 2.0 1451.0 ! Tsang 1991 c3h6+oh=pc3h5+h2o 2.11E+06 2.0 2778.0 ! Tsang 1991 c3h6+o=ch3co+ch3 5.00E+7 1.76 76.0 ! This Study c3h6+o=c2h5+hco 1.58E+07 1.76 -1216.0 ! Tsang 1991 c3h6+o=ac3h5+oh 5.24E+11 0.7 5884.0 ! Tsang 1991 c3h6+o=pc3h5+oh 1.20E+11 0.7 8959.0 ! Tsang 1991 c3h6+o=sc3h5+oh 6.03E+10 0.7 7632.0 ! Tsang 1991 c3h6+h=c2h4+ch3 4.00E+13 0.0 1302.0 ! This Study c3h6+h=ac3h5+h2 1.73E+05 2.5 2492.0 ! Tsang 1991 c3h6+h=sc3h5+h2 4.09E+05 2.5 9794.0 ! Tsang 1991 c3h6+h=pc3h5+h2 8.04E+05 2.5 12284.0 ! Tsang 1991 c3h6+ch3=ac3h5+ch4 2.22E+00 3.5 5675.0 ! Tsang 1991 c3h6+ch3=sc3h5+ch4 8.43E-01 3.5 11656.0 ! Tsang 1991 c3h6+ch3=pc3h5+ch4 1.35E+00 3.5 12848.0 ! Tsang 1991 c3h6+hco=ac3h5+ch2o 1.08E+07 1.9 17010.0 ! Tsang 1991 c3h6+o2=ac3h5+ho2 1.0e14 0.0 40000.0 ! This Study ch3chco+oh=ch2chco+h2o 4.00E+06 2.0 0.0 ! Marinov 1996 ch3chco+o=ch2chco+oh 7.60E+08 1.5 8500.0 ! Marinov 1996 ch3chco+h=ch2chco+h2 2.00E+05 2.5 2500.0 ! Marinov 1996 ch3chco+h=c2h5+co 2.00E+13 0.0 2000.0 ! Marinov 1996 ch3chco+o=ch3+hco+co 3.00E+07 2.0 0.0 ! Marinov 1996 ch2chcho+oh=hoc3h4o 2.92E+12 0.0 -1000.0 ! This Study ch2chcho+oh=chchcho+h2o 1.01e13 0.0 5936.0 ! This Study chchcho+o2=c2h2+co+ho2 2.00e12 0.0 0.0 ! This Study chchcho=c2h2+hco 1.00e14 0.0 33000.0 ! This Study hoc3h4o+o2=hoc3h4o3 1.00E+12 0.0 -1100.0 ! This Study hoc3h4o3=ch2o+chocho+oh 6.00E+10 0.0 26000.0 ! This Study hoc3h4o3+ho2=hoccqcho+o2 2.29E+11 0.0 -1550.0 ! This Study hoccqcho=ch2oh+chocho+oh 6.00E+14 0.0 42300.0 ! This Study ch2chcho+oh=ch2chco+h2o 9.24E+6 1.5 -962.0 ! Marinov 1996 ch2chcho+o=ch2chco+oh 7.24E+12 0.0 1970.0 ! Marinov 1996 ch2chcho+o=ch2hco+hco 5.01E+07 1.76 76.0 ! Marinov 1996 ch2chcho+h=ch2chco+h2 3.98E+13 0.0 4200.0 ! Marinov 1996 ch2chcho+h=c2h4+hco 2.00E+13 0.0 1500.0 ! Marinov 1996 ch2chcho+o2=ch2chco+ho2 3.00E+13 0.0 36000.0 ! Marinov 1996 ch2chco=c2h3+co 1.00E+14 0.0 34000.0 ! Marinov 1996 ch2chco+o=c2h3+co2 1.00E+14 0.0 0.0 ! Marinov 1996 ac3h5+o2=ac3h5o2 6.98E+22 -4.38 -5119.0 ! Bozzelli 1993 ac3h5+o2=ch2chcho+oh 1.82E+13 -0.41 22859.0 ! Bozzelli 1993 ac3h5+o2=ac3h4+ho2 4.99E+15 -1.4 22428.0 ! Bozzelli 1993 ac3h5+o2=ch2hco+ch2o 1.06E+10 0.34 12838.0 ! Bozzelli 1993 ac3h5+o2=c2h2+ch2o+oh 2.78E+25 -4.8 15468.0 ! Bozzelli 1993 ac3h5o2+ac3h5=ch2chch2o+ch2chch2o 2.40E+13 0.0 0.0 !This Study ac3h5o2+ho2=ac3h5o2h+o2 2.29E+11 0.0 -1550.0 !This Study ac3h5o2h=ch2chch2o+oh 6.00E+14 0.0 42300.0 !This Study ac3h5+ho2=ch2chch2o+oh 1.00E+13 0.0 0.0 !Tsang 1991 ch2chch2o+o2=ch2chcho+ho2 4.00E+10 0.0 1100.0 !This Study ch2chch2o+co=ac3h5+co2 4.68E+2 3.16 5380.0 !This Study ch2chcho+h(+m)=ch2chch2o(+m) 5.40E+11 0.454 2600. !This Study low/ 1.50E+30 -4.8 5560./ troe/0.78 94. 1555. 4200./ h2o/5./ ac3h5+oh=ac3h4+h2o 1.00E+13 0.0 0.0 ! Tsang 1991 ac3h5+h=ac3h4+h2 5.00E+13 0.0 0.0 ! Marinov 1996 ac3h5+h=c3h6 1.88E+26 -3.6 5468.0 ! Marinov 1996 ac3h5+o=ch2chcho+h 1.81E+14 0.0 0.0 ! Slagle 1992 ac3h5+ch3=ac3h4+ch4 3.02E+12 -0.32 -131.0 ! Tsang 1991 ac3h5+ac3h5=c6h10 3.00E+47 -8.0 19780.0 ! Tsang 1991 c6h10+oh=c6h9+h2o 4.16E+6 2.0 -298.0 ! This Study c6h9+ho2=ch2chcho+ac3h5+oh 5.0E+12 0.0 0.0 ! This Study pc3h5+o2=ch3hco+hco 1.09E+23 -3.29 3892.0 ! Marinov 1996 pc3h5+o2=ch3chco+h+o 1.60E+15 -0.78 3135.0 ! Marinov 1996 pc3h5+o=ch3chco+h 1.00E+14 0.0 0.0 ! Marinov 1996 pc3h5+h=pc3h4+h2 2.00E+13 0.0 0.0 ! Marinov 1996 pc3h5+oh=pc3h4+h2o 1.00E+13 0.0 0.0 ! Marinov 1996 pc3h5+h=ac3h5+h 1.00E+14 0.0 0.0 ! Marinov 1996 sc3h5+h=ac3h5+h 1.00E+14 0.0 0.0 ! Marinov 1996 sc3h5+o2=ch3co+ch2o 1.09E+22 -3.29 3892.0 ! Marinov 1996 sc3h5+o=ch2co+ch3 1.00E+14 0.0 0.0 ! Marinov 1996 sc3h5+h=pc3h4+h2 4.00E+13 0.0 0.0 ! Marinov 1996 sc3h5+oh=pc3h4+h2o 2.00E+13 0.0 0.0 ! Marinov 1996 ac3h4+h=h2ccch+h2 2.00E+7 2.0 5000.0 ! Marinov 1997 ac3h4+o=c2h4+co 1.34E+07 1.88 179.0 ! Marinov 1996 ac3h4+oh=h2ccch+h2o 1.00E+7 2.0 1000.0 ! Marinov 1997 ac3h4+ch3=h2ccch+ch4 1.50E+0 3.5 5600.0 ! Marinov 1997 ac3h4=pc3h4 1.48E+13 0.0 60401.0 ! Marinov 1997 pc3h4+h=h2ccch+h2 2.00E+7 2.0 5000.0 ! Marinov 1997 pc3h4+o=c2h4+co 1.50E+13 0.0 2102.0 ! Marinov 1996 pc3h4+oh=h2ccch+h2o 1.00E+7 2.0 1000.0 ! Marinov 1997 pc3h4+ch3=h2ccch+ch4 1.50E+0 3.5 5600.0 ! Marinov 1997 pc3h4+h=ch3+c2h2 5.12E+10 1.0 2060.0 ! Marinov 1997 pc3h4+h(+m)=sc3h5(+m) 6.50E+12 0.0 2000.0 ! Wagner 1972 low / 8.45E+39 -7.27 6577.0 / ! Marinov 1996 ac3h4+h(+m)=ac3h5(+m) 1.20E+11 0.69 3007.0 ! Tsang 1992 low / 5.56E+33 -5.0 4448.0 / ! Marinov 1996 ac3h4+h(+m)=sc3h5(+m) 8.49E+12 0.0 2000.0 ! Wagner 1972 low / 1.11E+34 -5.0 4448.0 / ! Marinov 1996 h2ccch+o2=ch2co+hco 3.00E+10 0.0 2868.0 ! Miller 1992 h2ccch+o=ch2o+c2h 1.40E+14 0.0 0.0 ! Pauwels 1995 h2ccch+h=c3h2+h2 5.00e+13 0.0 1000.0 ! Pauwels 1995 h2ccch+oh=c3h2+h2o 2.00E+13 0.0 0.0 ! Miller 1992 h2ccch+ch3=c3h2+ch4 2.00E+13 0.0 0.0 ! Marinov 1997 h2ccch+h(+m)=ac3h4(+m) 1.66E+15 -0.37 0.0 ! Marinov 1996 low / 3.36E+45 -8.52 6293.0 / ! Kiefer 1995 h2o/5.0/ h2/2.0/ co2/3.0/ co/2.0/ o2/2.0/ c2h2/2.0/ h2ccch+h(+m)=pc3h4(+m) 1.66E+15 -0.37 0.0 ! Marinov 1996 low / 8.78E+45 -8.9 7974.0 / ! Kiefer 1995 h2o /5.0/ h2/2.0/ co2/3.0/ co/2.0/ o2/2.0/ c2h2/2.0/ c3h2+o2=hcco+co+h 2.00E+12 0.0 1000.0 ! Pauwels 1995 c3h2+o=c2h2+co 1.00E+14 0.0 0.0 ! Pauwels 1995 c3h2+oh=c2h2+hco 5.00E+13 0.0 0.0 ! Miller 1992 n+no=n2+o 3.50E+13 0.00 330.0 ! GRI-Mech2.11 n+o2=no+o 2.65E+12 0.00 6400.0 ! GRI-Mech2.11 n+oh=no+h 7.33E+13 0.00 1120.0 ! GRI-Mech2.11 n2o+o=n2+o2 1.40E+12 0.00 10810.0 ! GRI-Mech2.11 n2o+o=2no 2.90E+13 0.00 23150.0 ! GRI-Mech2.11 n2o+h=n2+oh 4.40E+14 0.00 18880.0 ! GRI-Mech2.11 n2o+oh=n2+ho2 2.00E+12 0.00 21060.0 ! GRI-Mech2.11 n2o(+m)=n2+o(+m) 1.30E+11 0.00 59620.0 ! GRI-Mech2.11 low / 6.200e+14 .000 56100.00/ h2/2.00/ h2o/6.00/ ch4/2.00/ co/1.50/ co2/2.00/ c2h6/3.00/ ar/ .70/ no+ho2=no2+oh 2.11E+12 0.00 -480.0 ! GRI-Mech2.11 no+o+m=no2+m 1.06E+20 -1.410 0.0 ! GRI-Mech2.11 h2/2.00/ h2o/6.00/ ch4/2.00/ co/1.50/ co2/2.00/ c2h6/3.00/ ar/ .70/ no2+o=no+o2 3.90E+12 0.00 -240.0 ! GRI-Mech2.11 no2+h=no+oh 1.32E+14 0.00 360.0 ! GRI-Mech2.11 nh+o=no+h 5.00E+13 0.00 0.0 ! GRI-Mech2.11 nh+h=n+h2 3.20E+13 0.00 330.0 ! GRI-Mech2.11 nh+oh=hno+h 2.00E+13 0.00 0.0 ! GRI-Mech2.11 nh+oh=n+h2o 2.00E+09 1.20 0.0 ! GRI-Mech2.11 nh+o2=hno+o 4.61E+05 2.00 6500.0 ! GRI-Mech2.11 nh+o2=no+oh 1.28E+06 1.50 100.0 ! GRI-Mech2.11 nh+n=n2+h 1.50E+13 0.00 0.0 ! GRI-Mech2.11 nh+h2o=hno+h2 2.00E+13 0.00 13850.0 ! GRI-Mech2.11 nh+no=n2+oh 2.16E+13 -.230 0.0 ! GRI-Mech2.11 nh+no=n2o+h 4.16E+14 -.450 0.0 ! GRI-Mech2.11 nh2+o=oh+nh 7.00e+12 .000 .00 !GRI-Mech2.11 nh2+o=h+hno 4.60e+13 .000 .00 !GRI-Mech2.11 nh2+h=nh+h2 4.00e+13 .000 3650.00 !GRI-Mech2.11 nh2+oh=nh+h2o 9.00e+07 1.500 -460.00 !GRI-Mech2.11 nnh=n2+h 3.30e+08 .000 .00 !GRI-Mech2.11 dup nnh+m=n2+h+m 1.30e+14 -.110 4980.00 !GRI-Mech2.11 dup h2/2.00/ h2o/6.00/ ch4/2.00/ co/1.50/ co2/2.00/ c2h6/3.00/ ar/ .70/ nnh+o2=ho2+n2 5.00e+12 .000 .00 !GRI-Mech2.11 nnh+o=oh+n2 2.50e+13 .000 .00 !GRI-Mech2.11 nnh+o=nh+no 7.00e+13 .000 .00 !GRI-Mech2.11 nnh+h=h2+n2 5.00e+13 .000 .00 !GRI-Mech2.11 nnh+oh=h2o+n2 2.00e+13 .000 .00 !GRI-Mech2.11 nnh+ch3=ch4+n2 2.50e+13 .000 .00 !GRI-Mech2.11 h+no+m=hno+m 8.95e+19 -1.320 740.00 !GRI-Mech2.11 h2/2.00/ h2o/6.00/ ch4/2.00/ co/1.50/ co2/2.00/ c2h6/3.00/ ar/ .70/ hno+o=no+oh 2.50e+13 .000 .00 !GRI-Mech2.11 hno+h=h2+no 4.50e+11 .720 660.00 !GRI-Mech2,11 hno+oh=no+h2o 1.30e+07 1.900 -950.00 !GRI-Mech2.11 hno+o2=ho2+no 1.00e+13 .000 13000.00 !GRI-Mech2.11 cn+o=co+n 7.70e+13 .000 .00 !GRI-Mech2.11 cn+oh=nco+h 4.00e+13 .000 .00 !GRI-Mech2.11 cn+h2o=hcn+oh 8.00e+12 .000 7460.00 !GRI-Mech2.11 cn+o2=nco+o 6.14e+12 .000 -440.00 !GRI-Mech2.11 cn+h2=hcn+h 2.10e+13 .000 4710.00 !GRI-Mech2.11 nco+o=no+co 2.35e+13 .000 .00 !GRI-Mech2.11 nco+h=nh+co 5.40e+13 .000 .00 !GRI-Mech2.11 nco+oh=no+h+co 2.50e+12 .000 .00 !GRI-Mech2.11 nco+n=n2+co 2.00e+13 .000 .00 !GRI-Mech2.11 nco+o2=no+co2 2.00e+12 .000 20000.00 !GRI-Mech2.11 nco+m=n+co+m 8.80e+16 -.500 48000.00 !GRI-Mech2.11 h2/2.00/ h2o/6.00/ ch4/2.00/ co/1.50/ co2/2.00/ c2h6/3.00/ ar/ .70/ nco+no=n2o+co 2.85e+17 -1.520 740.00 !GRI-Mech2.11 nco+no=n2+co2 5.70e+18 -2.000 800.00 !GRI-Mech2.11 hcn+m=h+cn+m 1.04e+29 -3.300 126600.00 !GRI-Mech2.11 h2/2.00/ h2o/6.00/ ch4/2.00/ co/1.50/ co2/2.00/ c2h6/3.00/ ar/ .70/ hcn+o=nco+h 1.11e+04 2.640 4980.00 !GRI-Mech2.11 hcn+o=nh+co 2.77e+03 2.640 4980.00 !GRI-Mech2.11 hcn+o=cn+oh 2.13e+09 1.580 26600.00 !GRI-Mech2.11 hcn+oh=hocn+h 1.10e+06 2.030 13370.00 !GRI-Mech2.11 hcn+oh=hnco+h 4.40e+03 2.260 6400.00 !GRI-Mech2.11 hcn+oh=nh2+co 1.60e+02 2.560 9000.00 !GRI-Mech2.11 h+hcn+m=h2cn+m 1.40e+26 -3.400 1900.00 !GRI-Mech2.11 h2/2.00/ h2o/6.00/ ch4/2.00/ co/1.50/ co2/2.00/ c2h6/3.00/ ar/ .70/ h2cn+n=n2+ch2 6.00e+13 .000 400.00 !GRI-Mech2.11 c+n2=cn+n 6.30e+13 .000 46020.00 !GRI-Mech2.11 ch+n2=hcn+n 2.86e+08 1.100 20400.00 !GRI-Mech2.11 ch+n2(+m)=hcnn(+m) 3.10e+12 .150 .00 !GRI-Mech2.11 low / 1.300e+25 -3.160 740.00/ troe/ .6670 235.00 2117.00 4536.00 / h2/2.00/ h2o/6.00/ ch4/2.00/ co/1.50/ co2/2.00/ c2h6/3.00/ ar/ .70/ ch2+n2=hcn+nh 1.00e+13 .000 74000.00 !GRI-Mech2.11 ch2(s)+n2=nh+hcn 1.00e+11 .000 65000.00 !GRI-Mech2.11 c+no=cn+o 1.90e+13 .000 .00 !GRI-Mech2.11 c+no=co+n 2.90e+13 .000 .00 !GRI-Mech2.11 ch+no=hcn+o 5.00e+13 .000 .00 !GRI-Mech2.11 ch+no=h+nco 2.00e+13 .000 .00 !GRI-Mech2.11 ch+no=n+hco 3.00e+13 .000 .00 !GRI-Mech2.11 ch2+no=h+hnco 3.10e+17 -1.380 1270.00 !GRI-Mech2.11 ch2+no=oh+hcn 2.90e+14 -.690 760.00 !GRI-Mech2.11 ch2+no=h+hcno 3.80e+13 -.360 580.00 !GRI-Mech2.11 ch2(s)+no=h+hnco 3.10e+17 -1.380 1270.00 !GRI-Mech2.11 ch2(s)+no=oh+hcn 2.90e+14 -.690 760.00 !GRI-Mech2.11 ch2(s)+no=h+hcno 3.80e+13 -.360 580.00 !GRI-Mech2.11 ch3+no=hcn+h2o 9.60e+13 .000 28800.00 !GRI-Mech2.11 ch3+no=h2cn+oh 1.00e+12 .000 21750.00 !GRI-Mech2.11 hcnn+o=co+h+n2 2.20e+13 .000 .00 !GRI-Mech2.11 hcnn+o=hcn+no 2.00e+12 .000 .00 !GRI-Mech2.11 hcnn+o2=o+hco+n2 1.20e+13 .000 .00 !GRI-Mech2.11 hcnn+oh=h+hco+n2 1.20e+13 .000 .00 !GRI-Mech2.11 hcnn+h=ch2+n2 1.00e+14 .000 .00 !GRI-Mech2.11 hnco+o=nh+co2 9.80e+07 1.410 8500.00 !GRI-Mech2.11 hnco+o=hno+co 1.50e+08 1.570 44000.00 !GRI-Mech2.11 hnco+o=nco+oh 2.20e+06 2.110 11400.00 !GRI-Mech2.11 hnco+h=nh2+co 2.25e+07 1.700 3800.00 !GRI-Mech2.11 hnco+h=h2+nco 1.05e+05 2.500 13300.00 !GRI-Mech2.11 hnco+oh=nco+h2o 4.65e+12 .000 6850.00 !GRI-Mech2.11 hnco+oh=nh2+co2 1.55e+12 .000 6850.00 !GRI-Mech2.11 hnco+m=nh+co+m 1.18e+16 .000 84720.00 !GRI-Mech2.11 h2/2.00/ h2o/6.00/ ch4/2.00/ co/1.50/ co2/2.00/ c2h6/3.00/ ar/ .70/ hcno+h=h+hnco 2.10e+15 -.690 2850.00 !GRI-Mech2.11 hcno+h=oh+hcn 2.70e+11 .180 2120.00 !GRI-Mech2.11 hcno+h=nh2+co 1.70e+14 -.750 2890.00 !GRI-Mech2.11 hocn+h=h+hnco 2.00e+07 2.000 2000.00 !GRI-Mech2.11 hcco+no=hcno+co 2.35e+13 .000 0.00 !GRI-Mech2.11 ch3+n=h2cn+h 6.10e+14 -.310 290.00 !GRI-Mech2.11 ch3+n=hcn+h2 3.70e+12 .150 -90.00 !GRI-Mech2.11 nh3+h=nh2+h2 5.40e+05 2.400 9915.00 !GRI-Mech2.11 nh3+oh=nh2+h2o 5.00e+07 1.600 955.00 !GRI-Mech2.11 nh3+o=nh2+oh 9.40e+06 1.940 6460.00 !GRI-Mech2.11 ch3no2(+m)=ch3+no2(+m) 1.78E+16 0.0 58500.0 !Glaenzer 1972 low /1.26E+17 0.0 42000./ ch3no2+oh=ch2o+no+h2o 3.00E+6 2.0 2000.0 !This Study ch3no2+o=ch2o+no+oh 1.51E+13 0.0 5354.0 !Salter 1977 ch3no2+h=ch2o+no+h2 4.67E+12 0.0 3732.0 !Ko 1991 ch3no2+ch3=ch2o+no+ch4 7.08E+11 0.0 11140.0 !Ballod 1980 ac3h5+no2=c3h5no2 1.44E+50 -12.01 10260.0 !This Study c3h5no2+oh=ch2chcho+no+h2o 2.08E+6 2.0 -298.0 !This Study c3h5no2+h=ch2chcho+no+h2 1.15E+5 2.5 2492.0 !This Study c3h5no2+ch3=ch2chcho+no+ch4 1.48E+0 3.5 5675.0 !This Study hno2+h=no2+h2 2.40E+8 1.5 5087.0 !Dean 1997 hno2+o=no2+oh 1.70E+8 1.5 3020.0 !Dean 1997 hno2+oh=no2+h2o 1.20E+6 2.0 -596.0 !Dean 1997 hno2+ch3=no2+ch4 8.10E+5 1.87 4838.0 !Dean 1997 hno2=hono 1.30E+29 -5.47 52814.0 !Dean 1997 hono+ch3=no2+ch4 8.10E+5 1.87 5504.0 !Dean 1997 hono+oh=no2+h2o 1.26E+10 1.0 135.0 !Dean 1997 hono+o=no2+oh 1.21E+13 0.0 5962.0 !Dean 1997 hono+h=no2+h2 1.21E+13 0.0 7353.0 !Dean 1997 hono+hono=no+no2+h2o 1.02E+13 0.0 8540.0 !England 1975 no+oh(+m)=hono(+m) 2.00E+13 0.0 0.0 !Forster 1995 low /2.33E+23 -2.4 0.0/ oh+no2(+m)=hono2(+m) 2.40E+13 0.0 0.0 !Tsang 1991 low / 6.42E+32 -5.49 2351./ troe/0.525 1.0E-15 1.0E-15 1.0E+15/ h2o /5.0/ hono2+oh=no3+h2o 1.03E+10 0.0 -1240.0 !Lamb 1984 no3=no+o2 2.50E+6 0.0 12122.0 !Johnston 1986 no2+o+m=no3+m 2.94E+21 -2.0 0.0 !Atkinson 1989 no2+no2=no3+no 9.60E+9 0.73 20923.0 !Tsang 1991 dup no2+no2=no3+no 1.60E+12 0.0 26123.0 !Tsang 1991 dup ch3o+no(+m)=ch3ono(+m) 1.21E+13 0.0 -322.0 !Atkinson 1992 low / 2.70E+27 -3.50 0.0/ ch3o2+no=ch3o+no2 2.53E+12 0.0 -358.0 !Atkinson 1992 c2h5o2+no=ch3ch2o+no2 2.53E+12 0.0 -358.0 !This Study hoc2h4o2+no=ch2oh+ch2o+no2 2.53E+12 0.0 -358.0 !This Study ac3h5o2+no=ch2chch2o+no2 2.53E+12 0.0 -358.0 !This Study hoc3h6o2+no=ch2oh+ch3hco+no2 2.53E+12 0.0 -358.0 !This Study hoc3h4o3+no=chocho+ch2oh+no2 2.53E+12 0.0 -358.0 !This Study cccoo+no=cccoj+no2 2.11E+12 0.0 -358.0 c2coo+no=c2coj+no2 2.11E+12 0.0 -358.0 ch3o+no=ch2o+hno 6.00E+13 -0.6 0.0 !Frost 1990 ch3ch2o+no=ch3hco+hno 4.00E+13 -0.6 0.0 !This Study ch2chch2o+no=ch2chcho+hno 4.00E+13 -0.6 0.0 !This Study cccoj+no=cccho+hno 4.00E+13 -0.6 0.0 !This Study ch3+no(+m)=ch3no(+m) 2.17E+11 0.6 0.0 !Jodkowski 1993 low /2.06E+27 -3.50 0.0/ co+no2=co2+no 9.04E+13 0.0 33782.0 !Tsang 1991 ch3+no2=ch3o+no 1.50E+13 0.0 0.0 !Yamada 1981 ch3o+no2(+m)=ch3ono2(+m) 1.20E+13 0.0 0.0 !Atkinson 1992 low / 1.40E+30 -4.50 0.0/ c2h5+no2=ch3ch2o+no 2.70E+13 0.0 0.0 !Park 1983 ch2hco+no2=ch2o+hco+no 1.00E+13 0.0 0.0 !Barnhard 1991 ac3h5+no2=ch2chch2o+no 2.30E+13 0.0 0.0 !Slagle 1981 c6h9+no2=ch2chcho+ac3h5+no 2.00E+13 0.0 0.0 !This Study no2+ho2=hono+o2 6.31E+08 1.25 5000.0 !This Study ch3o+no2=ch2o+hono 4.00E+12 0.0 2285.0 !McCaulley 1985 ch3ch2o+no2=ch3hco+hono 2.70E+12 0.0 105.0 !This Study ch2chch2o+no2=ch2chcho+hono 2.70E+12 0.0 105.0 !This Study c2coj+no2=acetone+hono 2.70E+12 0.0 105.0 !This Study cccoj+no2=cccho+hono 2.70E+12 0.0 105.0 !This Study end